A novel method for cyanide quantification in human whole blood using ion chromatography with amperometric detection and its application to cyanide intoxication cases

Cyanide is a highly toxic agent that has been frequently used for suicide in South Korea. It is also used in various industrial fields, such as metal plating, in which many accidental cyanide intoxications have occurred. To overcome the disadvantages of conventional cyanide analysis methods, a simple and fast method for the analysis of cyanide in whole blood using ion chromatography (IC) with amperometric detection was developed in this study. Whole blood samples were deproteinized, diluted, and analyzed using an IC–amperometric detection system. The limits of detection and quantitation were 0.1 and 0.2 mg/L, respectively. The method showed good linearity in the range of 0.2 to 50 mg/L with R² > 0.99. The intra- and inter-assay precision and accuracy values were <10%. The established method was successfully applied to analyze whole blood samples from three cyanide intoxication cases.     

First Generation in Chilean Higher Education: Tension between Access and Inclusion in a Segmented University System

We analysed the Chilean university student selection processes, comparing ‘First Generation’ and ‘Continuist’ students, using the Chilean Higher Education population databases (2000–2015). Findings confirm that 60 percent of participants in the selection process are First Generation students. The data registers an increasing self-exclusion phenomenon. Of the students who did not take the selection test after enrolling, 80 percent are First Generation and 18 are enrolled in a selective university, compared to 44 in the Continuist conglomerate. These differences may be explained by cultural capital in the Bourdieu sense, in conjunction with a diversified, massified and marketalised higher education system.     

Differences in Physical Fitness and Body Composition Between Active and Sedentary Adolescents: A Systematic Review and Meta-Analysis

Journal of Youth and Adolescence - Previous research analyzing the differences in physical fitness and body composition between active and sedentary adolescents aged 12–16 has not provided...     

Parenting and Centrality: The Role of Life Meaning as a Mediator for Parenting and Language Broker Role Identity

Journal of Youth and Adolescence - Language brokering is a prevalent phenomenon in ethnic minority immigrant populations. Although accruing evidence points to the beneficial impacts of healthy role...     

Women Sustaining Community: The Politics of Agro-Ecology in Quilombo Tourism in Southern Brazil

This article analyses how a gendered perspective on community-based tourism (CBT) contributes to the realisation of identity and sovereignty of quilombos. It examines the potential sustainability of CBT coupled with agro-ecological practices within the context of gendered identity politics. Drawing from in-depth ethnographic and archival research conducted between February and July 2015 at Campinho da Independência (Rio de Janeiro, Brazil), the article discusses how female leaders integrate sustainable agro-ecological practices and CBT with environmental education in what they call ‘ethno-ecological tourism’. This approach to CBT strengthens a proudly defiant version of Afro-Brazilian ethnic identity vis-à-vis the state.     

“Jurisdictional Realization of Law” as Judicium: A Methodological Alternative,Beyond Deductive Application and Finalistic Decision

The proposed reflection intends to present the problem of judicial adjudication as a substantially-axiologically founded autonomous moment on the practical realization of law, and to explore this understanding in confrontation with external exigencies, mostly teleologically determined—hence, beyond strict deductive application, as a (normativistic-positivistic) syllogistic reference of facts to norms, and finalistically determined decision, as an option among possible alternatives to achieve specific aims. The main objective is to enter into a discussion on the methodological meaning of “integrity”, “hard cases” and “right answer”, as presented by Ronald Dworkin, and a critical reflection on the criticism(s) of that approach levelled by Neil MacCormick, so as to confront the relevance of principle and policy arguments, in order to bring about a different methodological approach, an alternative jurisprudentialist conception of adjudication, incorporating a practical-normative constitutive dialectics between legal controversy and legal system, such as that presented by Castanheira Neves. The focus will, then, be the legitimacy of the connection of arguments of principle and consequentialist arguments in adjudication, its selection and its justification, stating, therefore, a specifically assumed judicium, a judicative decision, having the legal system as its horizon of normative reference and of substantial and institutional autonomy.

     

Does the Electoral System Foster a Predominant Party System? Evidence from Turkey

This paper discusses the role of the electoral system in making the Justice and Development Party (AKP) dominant. Drawing on Sartori’s framework, we first clarify the concept of a predominant party system. Second, we examine the impact of the electoral system on the emergence of a predominant party system in Turkey. Analysing election results, we argue that the electoral system fosters dominance in three ways. First, a combination of electoral formula, national threshold and district threshold leads to over‐representation of large parties and under‐representation of small ones. Second, the fear of a wasted vote due to the high threshold prompts voters to support their second‐best option, which concentrates the votes among large parties. Finally, the electoral system increases electoral turnout rates by extending polarization.