Rapid analysis of malathion in blood using head space-solid phase microextraction and selected ion monitoring |
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| Institution: | 1. College of Animal Science and Veterinary Medicine, Henan Agricultural University, Zhengzhou 450000, China;2. School of Basic Medical Science, Xinxinag Medical University, Xinxiang 450003, China;3. College of Animal Science and Veterinary Medicine, Henan Institute of Science and Technology, Xinxiang 453003, China |
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| Abstract: | A simple and rapid method for analysis of malathion in blood was developed using head space-solid phase microextraction (HS-SPME) and gas chromatography mass spectrometry/ electron impact ionization-selected ion monitoring (GC-MS/EI-SIM). A vial containing a blood sample, ammonium sulphate, sulphuric acid and fenitrothion as an internal standard, was heated at 90 °C for 15 min. The extraction fiber of the SPME was exposed for 5 min in the head space of the vial. The compounds absorbed on the fiber were detached by exposing the fibre in the injection port of GC-MS. A straight calibration curve was obtained between malathion concentrations of 2.5 to 50.0 μg g−1 in blood. No interfering substances were found, and the time for analysis was 40 min for one sample. |
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