共查询到20条相似文献,搜索用时 109 毫秒
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激光拉曼光谱区分黑色圆珠笔字迹初探 总被引:8,自引:3,他引:5
针对现在广泛使用的薄层色谱分析技术带有破坏检材的缺点,提取采用激光拉曼光谱法进行无损检验,通过对收集的5个国家10种牌号样品进行初步比对分析,区分率达90%以上. 相似文献
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生物检材中毒鼠强的气相色谱测定法 总被引:7,自引:0,他引:7
本文介绍了生物检材中毒鼠强的气相色谱测定法。毒鼠强从生物检材中用丙酮提取,肝中回收率为81.86%,提取物浓缩定容后,取定量注入气相色谱仪中,色谱柱固定液为:1.5%OV-17,检测器为:NPD。本方法的最低检出限量为2mg。 相似文献
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Abstract: Thin layer chromatography (TLC) is a technique that is commonly employed in the forensic drug analysis of pharmaceutical preparations. Detection is typically accomplished using various visualization spray reagents. Conventional gas chromatography–mass spectrometry (GC‐MS) analysis is typically performed to confirm the TLC results. Depending on the drugs tested and the instrument conditions required, this confirmation can take up to an hour to complete. Direct analysis in real time (DART?) is an ionization source, coupled to an accurate‐mass time‐of‐flight mass spectrometer that has the capability to ionize materials under ambient conditions. To streamline analysis, the combination of TLC with DART? detection is proposed to screen and subsequently identify drug compounds, all from the same TLC plate. DART? confirmations of TLC analyses take <10 min to complete and compare favorably to GC‐MS in sensitivity and selectivity. This study validates the use of TLC‐DART in the forensic identification of the components of several pharmaceutical preparations. 相似文献
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刺激性毒物西阿尔(CR)的检验 总被引:1,自引:0,他引:1
目的简要介绍刺激性毒物西阿尔的物理、化学性质及检验方法;方法使用直接提取法对常见检材进行提取,使用TLC、GC/MS方法对其进行定性分析,以西阿尔在不同展开系统下的Rf值和特征质谱图作为定性依据;结果可快速准确的对西阿尔进行定性分析;结论该方法简便,易行,准确,可靠,可用于案件检验。 相似文献
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《Forensic science international》1988,37(1):47-53
Volatile compounds of 32 street heroin samples were analyzed by head space gas-chromatographic (HSGC) technique. The reliability of this procedure coupled with thin-layer chromatography (TLC), gas chromatography (GC), high performance liquid chromatography (HPLC), and its application to forensic casework (comparative sample analysis) is discussed. 相似文献
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Abstract: In recent years, Salvia divinorum has become a major focus by state legislatures throughout the United States looking to prohibit the sale of the psychoactive plant. After researching testing procedures presented in the literature and those employed by crime laboratories throughout the country, it was decided that thin layer chromatography (TLC) and gas chromatography/mass spectrometry (GC/MS) were the methods to use to analyze plant material for salvinorin A. With TLC, salvinorin A was detected from extracted plant material and was easily distinguishable from 13 other Salvia species as well as Cannabis sativa L. (marijuana). When using GC/MS, salvinorin A was best extracted from plant material with chloroform at ambient temperature when using a nonpolar solvent and acetone at ambient temperature when using a polar solvent. By utilizing these techniques, criminalists are now able to confirm the presence of salvinorin A in a submitted plant material suspected to be Salvia divinorum . 相似文献
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N V Veselovskaia E A Simonov V I Sorokin M A Drozdov B N Izotov T B Andriiako O B Dorogokupets E B Morozova A E Kovalenko 《Sudebno-meditsinskaia ekspertiza》1999,42(3):23-30
Methods for analysis of narcotics belonging to amphetamine methylene dioxy derivatives (MDD) are reviewed. The characteristics of these agents, their metabolism, and methods used for their detection and identification (TLC, GC, HPLC, GC/MS) are described. Methods for their extraction from biological objects (human urine and hair) are described. Efficacy of MDMA and MDEA from the urine by different extractants is assessed. The data demonstrate different potentialities for detection and identification of amphetamine MDD, including those in biological specimens (human urine and hairs), by numerous chromatographic methods. 相似文献
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尿中吗啡常见检测方法 总被引:3,自引:0,他引:3
本文介绍了尿中吗啡的常见检测方法,主要是化学反应法、免疫分析法、薄层色谱法、高效液相色谱法、气相色谱法、高效毛细管电泳法,气相色谱-质谱联用法以及最新检测方法分子印记-化学发光法。这些方法对海洛因依赖者的尿中吗啡可进行定性、定量检测,也可作为海洛因依赖者诊断和脱毒疗效评价的有效手段。 相似文献