Air Pollution from Cement Plants: Case Study on Particulate Matter in Bihar,India

Abstract

Environmental pollution and its impact is a major challenge for this age of industrialization and urbanization. It is becoming difficult to breathe fresh air in the cities and industrial areas. Both indoor and outdoor air quality is becoming worse day by day. A study has been conducted to find out the level of particulate matter concentration inside a village near to a cement plant located in Bihar, India to know the impact of the cement plant on the ambient environment. The present study clearly indicates that during night time particulate matter concentrations of the village environment were high compared to the day times. It is also observed that there is a high concentration of particulate matter in the ambient air compared to WHO air quality guideline values in both the cases(day times and night times) due to emission from the nearby cement plant. Hence this study suggests that the cement plants and other similar industries should take proper actions to maintain the air quality standard in the ambient areas.In the last part of the article some of the pollution control techniqueshas been discussed in brief which would be helpful to the industries to improve their environmental sustainability targets.     

Trends in the proportion of married women of reproductive age in Spain, 1887–1991

Using the Princeton nuptiality index I_m, we analyzed historical developments in the proportion of married women of reproductive age in Spain. We show the internal diversity in nuptiality patterns and offer an explanatory statistical model based on panel data analysis to identify the main variables influencing these changes over more than a century (1887–1991). We found that Spain has been the developed country with the greatest contrasts in its provincial nuptiality patterns (measured by I_m), although this diversity has lessened over the course of time. We also found that some socioeconomic variables (the gross domestic product per capita and the percentage of population living in cities) do not have a linear relationship with female nuptiality but rather have a U shape or an inverted U shape. This may partly account for some of the controversy that has raged on this topic over the past few decades on an international level.     

Identification of a disinterred grave by molecular and stable isotope analysis

Confirmation of a potential disinterred grave was sought by GC and GC/MS analyses of lipid extracts of whole soils and white particulate matter. Fatty acid profiles and concentrations determined for three of the soils correlated with the deposition of a large amount of exogenous organic matter, most likely adipocere and/or decomposed body fat. Determination of C_16:0 and C_18:0 fatty acid δ¹³C values by GC/C/IRMS revealed the input to be isotopically distinct from common British domesticated animals, plotting closely to values determined for adipose fat obtained from of a murder victim. By considering the difference between δ¹³C values (Δ¹³C_18:0–16:0) a potential isotopic proxy for identifying the source of adipocere (human) and adipose tissue was proposed.     

Mineralogical and elemental data for soil discriminating and geolocation tracing

One of the key tasks of soil analysis in forensic sciences is to provide information about its diversities and geolocation. In fact, soil analysis is relevant for forensic geologists. In this study, a total of 80 soil samples were collected from eight Chinese cities (10 samples per city). Different minerals and their relative percentages were analyzed by the X-ray diffraction (XRD) method. In addition, the relative amounts of montmorillonite, kaolinite, amphibole, feldspar, calcite, and dolomite provided information about the origin of a soil, either if it came from a northern or southern city of China. The oxide weight percentages of 10 elements of Al₂O₃, SiO_2, Fe₂O₃, K₂O, Na₂O, MgO, CaO, P₂O₅, MnO, and TiO₂ were also obtained by using X-ray fluorescence (XRF) from the 80 soil samples. Moreover, principal component analysis (PCA) and hierarchical clustering analysis (HCA) methods were performed for dimensionality reduction, elemental marker identification and soils classification to the city they came from purposes. The eighty soils analyzed in this study could be tracked correctly to their city of origin. The K-Nearest Neighbors (KNN) model was done to evaluate the prediction ability based on the soil elemental composition, and it was confirmed by cross validation methods. The results demonstrated that mineralogical and elemental composition can provide powerful information for soil discrimination and source tracing.     

A City‐wide Investigation of the Isotopic Distribution and Source of Tap Waters for Forensic Human Geolocation Ground‐truthing

Human geolocation is prefaced on the accuracy of the geographic precision of mapped isotopic values for drinking water. As most people live in cities, it becomes important to understand city water supplies and how the isotopic values uniquely reflect that city. This study investigated the isotopic distribution of δ²H and δ¹⁸O from sourced tap waters that were collected from across the Metro Vancouver (MV) area (n = 135). The results revealed that the isotopic values reflect their water sources with a range of 5.3‰ for δ¹⁸O_tap and 29.3‰ for δ²H_tap for MV. The results indicate that individual cities need higher resolution studies to determine their tap water isotopic ranges, and a good understanding of the water supply network itself for human geolocation work. With an extended high‐resolution understanding of each city, human tissue may be compared with more certainty for geolocation.     

Do deep and comprehensive regional trade agreements help in reducing air pollution?

Environmental concerns are increasingly being incorporated into regional trade agreements (RTAs) to promote environmental quality and ultimately ensure compatibility between trade and environmental policies. This occurs in a context where air pollution and its effects on human health are of major concern. This paper investigates whether the proliferation and depth of environmental provisions (EPs) in RTAs are associated with lower concentration levels of particulate matter. We present an index of EPs in RTAs that measures the breadth and depth of the provisions and use it to estimate the effect of ratifying RTAs with different levels of EPs on changes in PM_2.5 concentration levels in a panel of OECD countries over the 1999–2011 period. Using an instrumental variables strategy, we find that countries that have ratified RTAs with EPs show lower levels of PM_2.5 concentrations when we control for scale, composition and technique effects and for national environmental regulations. Moreover, the PM_2.5 concentration levels in the pairs of countries that belong to an RTA with EPs tend to converge for the country sample. The results also hold for a longer period of time (1990–2011) and a broader sample of 173 countries as well as for other pollutants, namely CO₂ and NO₂.     

The polymorphism of transferrin by ultrathin-layer isoelectric focusing. Tf phenotypes and TfC subtypes in the population of Padua

The distribution of Tf phenotypes in the population of Padua was investigated by ultrathin-layer isoelectric focusing. In our sample (n = 618) nine phenotypes, Tf C₁, C₂, C₃, C_3?1, C_2?1, C_3?2, C₁B, C₂B and C₁D, were observed and the following frequencies calculated: TfC₁ = 0.77837; TfC₂ = 0.1804; TfC₃ = 0.03641; TfB = 0.0040; TfD = 0.0008. These gene frequencies have been compared to those found in other populations. Analysis of 101 mother-child pairs was in agreement with an autosomal codominant mode of inheritance.     

Genetic variation of high-altitude Ecuadorian population using autosomal STR markers

Fifteen autosomal STRs were analyze in order to elucidate the differences between low and high land Ecuadorian population. Seven Ecuadorian geographic areas (Tisaleo-Mocha, Cañar, Quito, Rocafuerte, Santa Rosa, Guayaquil and Lago Agrio) from different altitude were selected for the study. After the analysis, little genetic distances were observed between all cities, the more distant cities (F_ST = 0.02354) were Rocafuerte at an elevation of 17 m.a.s.l. and Quito at 2850 m.a.s.l. and the similar cities (F_ST = 0.00033) were Rocafuerte (17 m.a.s.l.) and Santa Rosa (10 m.a.s.l). In conclusion, there is not a great genetic distance in the 15 STRs reported in high and low land Ecuadorian population, therefore previously reported frequencies could been used in identification and paternity cases under analysis.     

Estimating postmortem interval for human cadavers in a sub‐tropical climate using UV‐Vis‐near‐infrared Spectroscopy

Estimating postmortem interval (PMI) of surface found skeletal remains is challenging. This novel study used UV‐Vis‐NIR spectroscopy to scan soil collected from cadaver decomposition islands (CDIs) ranging from 15‐ to 963‐d postmortem and control soils. A decomposition product spectra model (DPS model) was constructed by deducting the control soil spectra from the CDI soil spectra for the estimation of postmortem indices: PMI (d), ADD₄, ADD₁₀, and ADD₂₀. The DPS model (n = 55) was calibrated and subjected to a full cross‐validation. Calibration R² and RPD for the DPS model ranged from 0.97 to 0.99 and from 6.1 to 9.9, respectively, for the four postmortem interval indices. Validation R² and RPD for the DPS model ranged from 0.73 to 0.80 and from 1.9 to 2.2, respectively. The DPS model estimated postmortem intervals for three test CDIs in a clay soil under perennial grassland (test set 1; n = 3) and six CDIs in a sandy soil under a loblolly pine forest (test set 2; n = 6). Test set 1 had PMI prediction ranges from ?69 to ?117 days, ?796 to +832 ADD₄, +552 to +2672 ADD₁₀, and ?478 to ?20 ADD₂₀ of observed PMI. Test set 2 PMI prediction ranged from ?198 to ?65 days, ?9923 to +2629 ADD₄, ?6724 to +1321 ADD₁₀, and ?2850 to +540 ADD₂₀ of observed PMI. Test set 2 had poor predictions for two CDIs, for all measures of postmortem indices resulting in discussion of sampling depth, effect of body mass index (BMI), and scavenging.     

Studies on the frequencies of PGM1, PGM3 and Es-D types from hair roots in Japanese subjects and the determination of these types from old hair roots

The frequencies in Japanese subjects are reported of hair roots type PGM₁, PGM₃ and Es-D, and the determination of these types from old hair roots. The gene frequencies were: PGM₁¹, 0.762; PGM₁², 0.230; PGM₁⁷, 0.008; PGM₃¹, 0.621; PGM₃², 0.379; Es-D¹, 0.625; and Es-D², 0.375. The old hair roots were analysed after storage at 25 °C, 4 °C and ?80 °C; the enzyme activities were detected and typed at 25 °C within PGM₁ 10 days, PGM₃ 4 days, and Es-D 4 days.     

Comparative analysis of 1-phenyl-2-propanone (P2P), an amphetamine-type stimulant precursor, using stable isotope ratio mass spectrometry: Presented in part as a poster at the 2nd meeting of the Joint European Stable Isotope User Meeting (JESIUM), Giens, France, September 2008

The isotope ratios of amphetamine type stimulants (ATS) depend as well on the precursor as the synthetic pathway. For clandestine production of amphetamine and methamphetamine, 1-phenyl-2-propanone (P2P, benzylmethylketone) is a commonly used precursor.Our aim was to determine the variation of the isotope ratios within precursor samples of one manufacturer and to compare seized samples of unknown sources to these values. δ¹³C_V-PDB, δ²H_V-SMOW and δ¹⁸O_V-SMOW isotope ratios were determined using elemental analysis (EA) and gas chromatography (GC) coupled to an isotope ratio mass spectrometer (IRMS). The comparison of all seized samples to the data of the samples of one manufacturer revealed considerable differences. The results show that IRMS provides a high potential in differentiating between precursors from different manufacturers for the clandestine production of ATS and identifying corresponding sources.     

Effectiveness of Femur Bone Indexes to Segregate Wild from Captive Minks,Mustela vison,and Forensic Implications for Small Mammals

Utilization of free‐living populations of endangered wildlife species is usually strictly prohibited or restricted. Farming of endangered species can provide products that are in demand as a countermeasure. A novel forensic issue arises because it becomes necessary to discriminate the origin of given wildlife products. We tested the effectiveness of five measurements and four indexes of femur bone using farmed minks (n = 40) and escapees (n = 32). Results showed all measurements, namely body mass (L_f), body length (M_f), femur mass (V_f), femur length (M_b), and femur volume (L_b), were highly discriminatory. However, they are susceptible to the influence of nutrition level and sex. Femur length index (I_fl), femur linear density (D_l), and femur volume density (D_v) eliminated the influence of level of nutrition and were highly effective. However, I_fl and D_l were influenced by sex (p = 0.000). Because D_v was not influenced by sex (p = 0.683) and was highly effective, it was the preferred index.     

Corrosion behaviour of four handguns in aqueous environments: Corrosion product characterization and effects on estimating the time since deposition

When a firearm has been disposed of in a body of water and becomes corroded, its appearance is altered and determining a time-since-immersion may be of import to the investigation. Therefore, in this study, the corrosion and mass loss of four handgun slides over a period of 180 days were examined. Solid-state characterization of the metals and their corrosion products via SEM/EDX and powder X-ray Diffraction (pXRD) was performed. The pXRDs were analyzed against the NIST Powder Diffraction Database to determine the crystalline phases. Filings from the SS416 standard, Llama and Ruger handgun slide predominantly consisted of iron alloys. After 180-days in solution, pXRD indicated that the adherent corrosion products consisted of 1) γ-FeOOH and 2) iron oxide (Fe₃O₄ or Fe₂O₃). Additionally, pXRD analysis indicated that the adherent corrosion products of the SS416 standard also consisted of CrO₃. Metal filings from the Raven and Jennings handgun slides were a mixture of iron–nickel–zinc and EDX and pXRD analyses of the corrosion products, when submersed in deionized water, indicated that the products consisted of: 1) γ-FeOOH, 2) iron oxide (Fe₃O₄ or Fe₂O₃), and 3) ZnFe₂O₄ or ZnO; where the Jennings adherent rust contained ZnFe₂O₄ and the Raven adherent rust contained ZnO. Further, pXRD of the corrosion products from these alloys, when submersed in 25 PSU (Practical Salinity Unit) solution, indicated that the products consisted of: 1) ZnO, 2) Zn(OH)₂, 3) α-Ni(OH)₂, and 4) NaCl.The data thus indicated that both metal composition and the presence of chloride ions had significant impacts on rates and products of corrosion and suggest that the presence of Cl^? changes not only the rate of corrosion, but also the corroding species itself. While mechanisms and rates of the chloride driven corrosion processes offer explanations as to the different oxides and hydroxides observed between immersion conditions, they do not offer an explanation for the differences observed between handguns. Therefore, utilizing a general approach where surface area coverage of corrosion products is the sole consideration is not sufficient to determine time-since-immersion. Attempts to determine a time-since-immersion would require a priori knowledge of the mechanism of corrosion for a given metal mixture within a specified environment. The results described herein give indications as to the possible corrosion mechanism driving the process in high and low Cl^? environments and show the necessity of including the metal composition, rust composition and ion concentration in any models that attempt to elucidate the time-since-immersion of handguns for forensic applications.     

Discrimination Between Infant and Adult Bloodstains Using Micro‐Raman Spectroscopy: A Preliminary Study

In the present study, we used micro‐Raman spectroscopy with high‐resolution analysis to discriminate between bloodstains from infants and bloodstains from adults. Raman peaks were detected at 674, 754, 976, 1002, 1105, 1127, 1176, 1248, 1340, 1368, 1390, 1560, and 1611 cm^?1; these peaks were derived from hemoglobin, albumin, and glucose. However, a peak was obtained at 1105 cm^?1, which was assigned to histidine; this peak was observed only for bloodstains from adults. Human adult hemoglobin (HbA) is composed of an α₂β₂ tetramer structure, whereas human fetal hemoglobin (HbF) is composed of an α₂γ₂. Therefore, the lack of a Raman peak at 1105 cm^?1 in bloodstains from infants indicates the possibility of two histidine substitutions (His116Ile and His143Ser) in the γ chain of HbF. This study discriminates between bloodstains from infants and bloodstains from adults using micro‐Raman spectroscopy, with beneficial implications in forensic science.     

Gas dispersal potential of bedding as a cause for sudden infant death

We assessed the gas dispersal potential of bedding articles used by 14 infants diagnosed with sudden unexpected infant death at autopsy. Of these cases, eight exhibited FiCO₂ values greater than 10% within 2.5 min, six of which were found prone and two supine. The results demonstrated that these eight beddings had a high rebreathing potential if they covered the babies’ faces. We did not, however, take into account in our model the large tissue stores of CO₂. As some bicarbonate pools will delay or suppress the increase of FiCO₂, the time–FiCO₂ graphs of this study are not true for living infants. This model, however, demonstrated the potential gas dispersal ability of bedding. The higher the FiCO₂ values, the more dangerous the situation for rebreathing infants. In addition, FiO₂ in the potential space around the model's face can be estimated mathematically using FiCO₂ values. The FiO₂ graph pattern for each bedding item corresponded roughly to the inverse of the FiCO₂ time course. The FiO₂ of the above eight cases decreased by 8.5% within 2.5 min. Recent studies using living infants placed prone to sleep reported that some babies exhibited larger decreases in FiO₂ than increases observed in FiCO₂. While the decrease of FiO₂ in our model is still theoretical, CO₂ accumulation and O₂ deprivation are closely related. If a striking O₂ deficiency occurs in a short period, babies can lose consciousness before an arousal response is evoked and all infants could be influenced by the poor gas dispersal of bedding; the main cause of sudden death in infancy would thus be asphyxia. When the bedding is soft, the potential for trapping CO₂ seems to be high; however, it is impossible to assess it by appearance alone. We sought to provide some objective indices for the assessment of respiratory compromise in relation to bedding using our model. When a baby is found unresponsive with his/her face covered with poor gas dispersal bedding, we should consider the possibility of asphyxia.     

Reproductive behaviour in the Lutheran urban family from historical Poland (the Parish of St. Peter from Poznań, the second half of the nineteenth century)

Fertility and reproductive behaviour in the nineteenth-century Lutheran family from the city of Poznań was characterized. Use was made of the St. Peter parish (Peterkirche) registers from 1840s to 1870s, upon which reconstructions of the individual histories of 463 families were based. Fertility was assessed on the basis of the length of between-birth intervals according to their order and age of women. Next, the age-specific fertility rates of women f_x and Coale Index of marital fertility I_g were calculated. From a seasonal rhythm of both marital and illegitimate births, and reconstructed on the basis of these, the annual rhythm of marital and prenuptial conceptions were characterized. In the Lutheran Parish of St. Peter from the city of Poznań illegitimate births and prenuptial conceptions accounted for almost 10% and over 5% of all births, respectively. Lack of seasonality for marital births was noted here. Illegitimate births, by contrast, were characterized by a statistically significant annual rhythm: their maximum was noted in April, which was a result of conceptions during summer. The average woman with completed reproduction cycle gave birth to the first and to the last child at the ages of 29 and 40 years, respectively. She therefore used 32% of her whole reproductive period. Late age of birth of the first child was associated with late age of marriage of women (on average 28 years). An average woman with completed reproduction gave birth to 4.8 children. The average length of the protogenesic interval was 18 months. The highest fertility occurred in women aged between 20 to 29 years. The value of the I_g index was 0.67, and proved a lack of birth control rather than conscious birth regulation. Generally, Lutheran women from Poznań were characterized by fairly high reproductive potential.     

An ontology-based approach for the reconstruction and analysis of digital incidents timelines

Due to the democratisation of new technologies, computer forensics investigators have to deal with volumes of data which are becoming increasingly large and heterogeneous. Indeed, in a single machine, hundred of events occur per minute, produced and logged by the operating system and various software. Therefore, the identification of evidence, and more generally, the reconstruction of past events is a tedious and time-consuming task for the investigators. Our work aims at reconstructing and analysing automatically the events related to a digital incident, while respecting legal requirements. To tackle those three main problems (volume, heterogeneity and legal requirements), we identify seven necessary criteria that an efficient reconstruction tool must meet to address these challenges. This paper introduces an approach based on a three-layered ontology, called ORD2I, to represent any digital events. ORD2I is associated with a set of operators to analyse the resulting timeline and to ensure the reproducibility of the investigation.     

Murder, Nonnegligent Manslaughter, and Spatial Autocorrelation in Mid-South Counties

In this paper we explore to what extent county murder and nonnegligentmanslaughter rates in the midsouth are spatially autocorrelated, usinga variety of spatial autocorrelation tests. The data are 3-year averages ofUCR murder and nonnegligent manslaughter rates from the 383 midsouthcounties. Moran's I statistics show a statistically significant amountof spatial autocorrelation in the murder and nonnegligent manslaughter ratesamong the 383 midsouth counties. G statistics, however, fail to detect aglobal pattern in this region. We also compute G _i statistics and localMoran's I statistics with these data and detect some patterns oflocalized spatial autocorrelation. We estimated and compared an MLE spatiallag model and an OLS model with constructs informed by socialdisorganization theory. The regression analysis failed to detect anysignificant spatial effects for the midsouth counties.     

Measuring Crime Concentration Across Cities of Varying Sizes: Complications Based on the Spatial and Temporal Scale Employed

Objectives

We argue that assessing the level of crime concentration across cities has four challenges: (1) how much variability should we expect to observe; (2) whether concentration should be measured across different types of macro units of different sizes; (3) a statistical challenge for measuring crime concentration; (4) the temporal assumption employed when measuring high crime locations.

Methods

We use data for 42 cities in southern California with at least 40,000 population to assess the level of crime concentration in them for five different Part 1 crimes and total Part 1 crimes over 2005–2012. We demonstrate that the traditional measure of crime concentration is confounded by crimes that may simply spatially locate due to random chance. We also use two measures employing different temporal assumptions: a historically adjusted crime concentration measure, and a temporally adjusted crime concentration measure (a novel approximate solution that is simple for researchers to implement).

Results

There is much variability in crime concentration over cities in the top 5 % of street segments. The standard deviation across cities over years for the temporally adjusted crime concentration measure is between 10 and 20 % across crime types (with the average range typically being about 15–90 %). The historically adjusted concentration has similar variability and typically ranges from about 35 to 100 %.

Conclusions

The study provides evidence of variability in the level of crime concentration across cities, but also raises important questions about the temporal scale when measuring this concentration. The results open an exciting new area of research exploring why levels of crime concentration may vary over cities? Either micro- or macro- theories may help researchers in exploring this new direction.

     

Practical benzylation of N,N-substituted ethanolamines related to chemical warfare agents for analysis and detection by electron ionization gas chromatography–mass spectrometry

The benzylation of three low molecular weight N,N-disubstituted ethanolamines related to chemical warfare agents (CWAs) to furnish derivatives with improved gas chromatography-mass spectrometry (GC-MS) profiles is described. Due to their low molecular weight and polar nature, N,N-disubstituted ethanolamines are notoriously difficult to detect by routine GC-MS analyses during Organisation for the Prohibition of Chemical Weapons (OPCW) proficiency tests (PTs), particularly in scenarios when they are present at low levels (~1–10 ppm) amidst more abundant interferences. Our studies revealed that the optimal derivatization conditions involved the treatment of the ethanolamine with benzyl bromide in the presence of an inorganic base (e.g., Na₂CO₃) in dichloromethane at 55°C for 2 h. This optimized set of conditions was then successfully applied to the derivatization of N,N-dimethylethanolamine, N,N-diethylethanolamine and N,N-diisopropylethanolamine present separately at 1 and 10 μg/mL concentrations in a glycerol-rich matrix sample featured in the 48th OPCW PT. The benzylated derivatives of the three ethanolamines possessed retention times long enough to clear the massive glycerol-containing matrix interferences. The protocol herein is introduced as an alternative method for derivatization of these CWA and pharmaceutically important species and should find broad applicability in laboratories where routine forensic analysis is carried out.