Multiple stable isotope characterization as a forensic tool to distinguish acid scavenger samples

Acid scavengers are frequently used as stabilizer compounds in a variety of applications. When used to stabilize volatile compounds such as nerve agents, the lower volatility and higher stability of acid scavengers make them more persistent in a post-event forensic setting. Compound-specific isotope analysis of carbon, nitrogen, and hydrogen in three acid-scavenging compounds (N,N-diethylaniline, tributylamine, and triethylamine) were used as a tool for distinguishing between different samples. Combined analysis of multiple isotopes improved sample resolution, for instance differentiation between triethylamine samples improved from 80% based on carbon alone to 96% when combining with additional isotope data. The compound-specific methods developed here can be applied to instances where these compounds are not pure, such as when mixed with an agent or when found as a residue. Effective sample matching can be crucial for linking compounds at multiple event sites or linking a supply inventory to an event.     

An inconclusive digital audio authenticity examination: a unique case

This case report sets forth an authenticity examination of 35 encrypted, proprietary-format digital audio files containing recorded telephone conversations between two codefendants in a criminal matter. The codefendant who recorded the conversations did so on a recording system he developed; additionally, he was both a forensic audio authenticity examiner, who had published and presented in the field, and was the head of a professional audio society's writing group for authenticity standards. The authors conducted the examination of the recordings following nine laboratory steps of the peer-reviewed and published 11-step digital audio authenticity protocol. Based considerably on the codefendant's direct involvement with the development of the encrypted audio format, his experience in the field of forensic audio authenticity analysis, and the ease with which the audio files could be accessed, converted, edited in the gap areas, and reconstructed in such a way that the processes were undetected, the authors concluded that the recordings could not be scientifically authenticated through accepted forensic practices.     

Hyperbolic Time Discounting, Offender Time Preferences and Deterrence

Objectives

This study examines the phenomena of intertemporal decision making??decisions involving costs and benefits that occur at different points in time. Two models of intertemporal time discounting are the exponential and hyperbolic models. Previous work in behavioral economics and psychology is relied on to make the case that the discounting of delayed outcomes (both gains and losses) may be hyperbolic rather than exponential.

Methods

Data were collected from 478 university undergraduate students who responded to a hypothetical scenario involving drunk driving. The potential gains and losses of drunk driving were delayed at five different intervals from ??tonight?? to ??10?years from now??, respondents were also asked to provide estimates of both the risk they would get caught if they did drink and drive and the probability that they would drink and drive under the conditions described in the scenario.

Results

Our results imply that individuals have hyperbolic time preferences for both rewards and gains, and that??unlike severity, the effect of which may be muted by risk??these discount functions appear to be operating independently of changes in the risk certainty of detection. Consistent with hyperbolic discounting, for example, when the benefit of drinking and driving was delayed by 1?week the self-reported intention to drink and drive increased by nearly 10%, however, when the gain was delayed by one month, intentions to drink and drive increased by only 4%. A smaller effect was found for delayed costs.

Conclusions

Avenues for additional research include the possibility of negative discount rates and the implications of persons?? awareness of their discount rates.     

Radiocarbon Analysis of Human Remains: A Review of Forensic Applications

Radiocarbon analysis of organic materials, with the comparison of values with those of the post‐1950 modern bomb curve, has proven useful in forensic science to help evaluate the antiquity of evidence. Applications are particularly helpful in the study of human remains, especially with those displaying advanced decomposition of soft tissues. Radiocarbon analysis can reveal if the remains relate to the modern, post‐1950 era and if so, also provide information needed to evaluate the death and birth date. Sample selection and interpretation of results must be guided by knowledge of the formation and remodeling of different human tissues, as well as contextual information and the approximate age at death of the individual represented. Dental enamel does not remodel and thus captures dietary radiocarbon values at the time of juvenile formation. Most other human tissues do remodel but at differing rates and therefore collectively offer key information relative to the estimation of the death date.     

Impact of Intimate Partner Violence on Women’s Mental Health

This study aimed to explore the mental health needs of women residing in domestic violence shelters; more specifically, we aimed to identify commonalities and differences among their mental health needs. For this purpose, qualitative and quantitative data was collected from 35 women from a Midwestern domestic violence shelter. Hierarchical clustering was applied to quantitative data, and the analysis indicated a three-cluster solution. Data from the qualitative analysis also supported the differentiation of women into three distinct groups, which were interpreted as: (A) ready to change, (B) focused on negative symptoms, and (C) focused on feelings of guilt and self-blame.     

Alexis de Tocqueville on the Covenantal Tradition of American Federal Democracy

Perhaps no analyst of democracy's potentials for despotism andself-government understood better than Alexis de Tocquevillethe importance of the "favorable circumstances" of America'srepublican and religious origins. America's covenantal heritageinspired the public philosophy of federal liberty and the federalprinciple used to establish governments and political associationsin colonial New England. The Puritans, Tocqueville explained,created the bonds and the liberties of citizenship by theirassent to eternal, transcendent principles, as well as by theirconsent to government. The principles of covenant ultimatelyprovided the institutional and conceptual foundation of constitutionalgovernment, making America's federal democracy less vulnerableto possessive individualism and democratic despotism. Federalprinciples fostered an important indirect role for religionin American politics. Tocqueville not only analyzed the tensionbetween the requirements of faith and democratic norms, butalso distinguished covenantal ways of negotiating these concernsfrom the approach taken by later advocates of religious freedom,fames Madison and Thomas Jefferson. He argued that federalism'smoral foundations will be difficult to preserve if this tensionis resolved in ways that promote individual autonomy by underminingcovenantal thinking.     

Children’s Exposure to Partner Violence in Homes Where Men Seek Help for Partner Violence Victimization

In the last several decades, the field of family violence has paid increasing attention to children’s exposure to partner violence (CEPV). Most of this research has focused on the children of women seeking help for partner violence (PV) victimization. In this paper we examine exposure to PV among children of men who sought help for PV victimization (n?=?408), as compared with children of men in a population-based sample (n?=?666). We examined children’s exposure to psychological, physical, and sexual PV and also examined CEPV that is perpetrated by women, men, or both partners. The results show that CEPV is higher among children of helpseeking men than among children of men from the population-based sample, and that most of that PV is perpetrated by the female partner. We did not find differences in CEPV based in child age or gender. We discuss implications for the field of family violence professionals.     

Reflections on calling and careers in community psychology

The current essay discusses the narratives of five community psychologists from the perspective of a career "calling." Each of the essays highlight different components of a calling: employing deep discernment to know the right path for oneself; experiencing a calling to do one's work, an invitation to which we choose to respond; serving community; discovering your quintessential self or "genius"; and using your gifts for the common good. Moreover, the author discusses how the essays not only illustrate calling, but also the emergence of confidence and the subjective career.     

'These boots are made for walking': why most divorce filers are women

Because of the financial and social hardship faced after divorce,most people assume that generally husbands have instigated divorcesince the introduction of no-fault divorce. Yet women file fordivorce and are often the instigators of separation, despitea deep attachment to their children and the evidence that manydivorces harm children. Furthermore, divorced women in largenumbers reveal that they are happier than they were while married.They report relief and certainty that they were right in leavingtheir marriages. This fundamental puzzle suggests that the incentivesto divorce require a reexamination, and that the forces affectingthe net benefits from marriage may be quite complicated, andperhaps asymmetric between men and women. This paper considerswomen's filing as rational behavior, based on spouses' relativepower in the marriage, their opportunities following divorce,and their anticipation of custody.