Public Sector Reform Knowledge Production: Validation and Evidence as 'Agreement'

In this article I draw on public sector reform knowledge in the United States, New Zealand and Australia. I argue that we, as practitioners, do not need to immerse ourselves in academic debates about 'positivism' or 'post-positivism'. These are frameworks for examining knowledge capable of validation. Instead, we are now engaged in using diverse forms of knowledge to spread the word on what works and does not work to deliver outcomes. Such knowledge is not above reproach; it is not acceptable merely because it exists but nor is it unacceptable because it cannot be rigorously validated in a positivist way.     

"Nukes for Sale Cheap?" Purchasing Peace with North Korea

What impact can economic incentives have on difficult international security problems, such as nuclear proliferation? This article first discusses theories of the effectiveness of incentives. It then examines the case of the 1994 Agreed Framework accord between the United States and North Korea. It argues that, despite cheating by Pyongyang, the American effort to use incentives in this case was on balance more successful than many now believe, especially in view of the bleak alternatives. If incentives can have an impact in such a "least likely" case, there is reason to believe they could be helpful in resolving other cases of proliferation.     

GC–MS studies on acylated derivatives of 3-methoxy-4-methyl- and 4-methoxy-3-methyl-phenethylamines: Regioisomers related to 3,4-MDMA

A series of side chain regioisomers of 3-methoxy-4-methyl- and 4-methoxy-4-methyl-phenethylamines have mass spectra essentially equivalent to the controlled drug substance 3,4-methylenedioxymethamphetamine (3,4-MDMA), all have molecular weight of 193 and major fragment ions in their electron ionization mass spectra at m/z 58 and 135/136. The acetyl, propionyl and trifluoroacetyl derivatives of the primary and secondary regioisomeric amines were prepared and evaluated in GC–MS studies. The mass spectra for these derivatives were significantly individualized and the resulting unique fragment ions allowed for specific side chain identification. The trifluoroacetyl derivatives provided more fragment ions for molecular individualization among these regioisomeric substances. These trifluoroacetyl derivatives showed excellent resolution on a non-polar stationary phase such as Rtx-1.     

Comparison of gunshot wounds and field-tipped arrow wounds using morphological criteria and chemical spot tests

Arrow wounds represent an unusual class of wounds rarely seen by most death investigators. Although the edged, broadhead-tipped arrow produces a wound usually characteristic of archery/crossbow weapons, the plain, field-tipped arrow wound can be confused with gunshot injuries in those cases in which powder residue or firearm projectiles or fragments or both are not recovered. We present a case of a deer carcass with a wound of uncertain firearm or archery origin which initiated a comparison of firearm wounds and archery wounds on fresh road-killed deer. We found the following features to be valuable in the differentiation of gunshot wounds and field-tipped archery wounds: First, the majority of the gunshot wounds (but none of the arrow wounds) had identifiable, macroscopic, wipe-off material and chemically identifiable wipe-off residue by spot test. Second, the archery wound defects had very inconspicuous abrasion rings as compared to the often prominent abrasion rings of gunshot wounds. Third, the actual central defect in the archery wounds was more likely to be oblong or slit-like compared to the gunshot wound defects, which were more likely to be round.