TOF‐SIMS Analysis of Red Color Inks of Writing and Printing Tools on Questioned Documents

Time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) is a well‐established surface technique that provides both elemental and molecular information from several monolayers of a sample surface while also allowing depth profiling or image mapping to be performed. Static TOF‐SIMS with improved performances has expanded the application of TOF‐SIMS to the study of a variety of organic, polymeric, biological, archaeological, and forensic materials. In forensic investigation, the use of a minimal sample for the analysis is preferable. Although the TOF‐SIMS technique is destructive, the probing beams have microsized diameters so that only small portion of the questioned sample is necessary for the analysis, leaving the rest available for other analyses. In this study, TOF‐SIMS and attenuated total reflectance Fourier transform infrared (ATR‐FTIR) were applied to the analysis of several different pen inks, red sealing inks, and printed patterns on paper. The overlapping areas of ballpoint pen writing, red seal stamping, and laser printing in a document were investigated to identify the sequence of recording. The sequence relations for various cases were determined from the TOF‐SIMS mapping image and the depth profile. TOF‐SIMS images were also used to investigate numbers or characters altered with two different red pens. TOF‐SIMS was successfully used to determine the sequence of intersecting lines and the forged numbers on the paper.     

Fatal Intoxication with Toluene Due to Inhalation of Glue

Two cases of fatal intoxications with toluene due to glue sniffing are described. In case 1, the autopsy did not indicate cause of death, while in case 2, the cause of death was determined to possibly be due to mechanical asphyxia by drowning. As the decedents had a history of glue sniffing, toxicological analyses were performed. Using gas chromatography with flame ionization detector and gas chromatography/mass spectrometry (GC/MS) with headspace method, toluene was detected in biological samples. Toluene ranged from 3.81 to 20.97 μg/g, with the highest concentrations observed in liver and brain (13.82–20.97 μg/g) in both cases. Based upon this data, the cause of death in both cases was determined to be toluene poisoning. Toxicological investigations are extremely important and should be considered mandatory in all deaths thought to be due to volatile substance abuse, as well as all deaths that are thought to be due to poisoning in young people.     

Blow Flies from Forest Fragments Embedded in Different Land Uses: Implications for Selecting Indicators in Forensic Entomology

Given the general expectation that forest loss can alter biodiversity patterns, we hypothesize that blow fly species abundances differ in a gradient of native vegetation cover. This study was conducted in 17 fragments across different landscapes in central Brazil. Different land cover type proportions were used to represent landscape structure. In total, 2334 specimens of nine species of Calliphoridae were collected. We used principal component analysis (PCA) to reduce dimensionality and multicollinearity of the landscape data. The first component explained 70%, and it represented a gradient of forest‐pasture land uses. Alien species showed a wide distribution in different fragments with no clear relationship between the abundance values and the scores of PCA axes, whereas native species occurred only in areas with a predominance of forest cover. Our study revealed that certain native species may be sensitive to forest loss at the landscape scale, and they represent a bioindicator in forensic entomology.     

Improving Luminol Blood Detection in Forensics

The aim of this study was to develop chemical improvements to the original Weber protocol, in order to increase the intensity and time length of light emission and to eliminate false‐positive reactions. The intensity and duration of light were measured on serial blood dilutions using a plate reader chemiluminometer. Blood stains of various concentrations were impregnated in pure cellulose, dried, and luminol solution was added with/without the potential enhancers. An in silico study was also conducted, aiming to demonstrate the enhancing mechanism of hemoglobin denaturation using 8 M urea. The luminol blood detection test revealed important improvements after urea pretreatment or in the presence of monochloro‐triazinyl‐β‐cyclodextrin. This approach also eliminated the false‐positive reaction from sodium hypochlorite. These improvements could provide a higher sensitivity under particular circumstances such as old or washed blood stains, leading to a better localization for further DNA typing and higher quality photographic analysis.     

Facts,Preferences, and Doctrine: An Empirical Analysis of Proportionality Judgment

Legal proportionality is one of the most important principles for adjudicating among conflicting values. However, rather little is known about the factors that play a role in the formation of proportionality judgments. This research presents the first empirical analysis in this regard, relying on a sample of 331 legal experts (lawyers and legal academics). The policy domain addressed by the experiment is the antiterrorist military practice of targeted killings, which has been the subject of a legal debate. Our experimental findings suggest that proportionality judgments are receptive to normatively relevant facts. We also find strong correlational evidence for the effect of ideological preferences on such judgments. These results are consistent for two proportionality doctrines. We suggest that proportionality judgment is anchored jointly in the experts’ policy preferences and the facts of the case. We outline the implications of the findings for the psychological and legal literature.     

Convenient and Inconvenient Truths in Family Law: Preventing Scholar‐Advocacy Bias in the Use of Social Science Research for Public Policy

This is the second of two articles on the risks of advocacy bias in the reporting of research findings when boundaries are blurred between social science research and advocacy in the pursuit of public policy. In the first article we identify common ways in which social science researchers and reviewers of research—wittingly or unwittingly—can become advocates for ideological positions and social policies at the expense of being balanced reporters of research evidence. The first article discusses the difference between truth in social science and truth in law and identifies a range of scholar‐advocacy strategies that bias research evidence, illustrated by recent debates about overnight parenting of infants and toddlers. In this second article we show how biased research evidence by scholar advocates results in increased confusion and controversy that diminishes the credibility of all parties and stalemates progress in the field, using a case illustration of intimate partner violence in family court. We also show how adherence to scientific methods prevents the misuse of research and suggest a number of collaborative, integrative measures that can help transcend the adversarial stalemate. In a look to the future we consider some unbiased, standardized ways of assessing the strength and generalizability of research evidence.     

L'affaire Groupaction: un cas de politisation de la Fonction publique fédérale?

Sommaire: l affaire Groupaction met en relief deux formes de politisation de la Fonction publique fédérale: l'une partisane, l'autre structurelle. La politisation de type partisan et I'intégration de personnel politique au sein de la Fonction publique via l'article 39 de laLoi sur la Fonction publique sont devenues des phénoménes plus répandus au cours des demiéres années. La notion de politisation structurelle sou‐ligne comment la Fonction publique canadienne n'est pas politiquement neutre face à ceux et celles qui veulent dé‐faire l'ordre fédéral. Même si elle ne constitue pas une excuse justifiant le type de comportement observé dans l'affaire Groupaction, la politisation structurelle founit le contexte pour comprendre pourquoi certains fonc‐tionnaires ont pené qu'il pouvait être légitime de contourner les régles pour préServer I'unité nationale. Abstract: The Groupadion affair draws attention to two forms of politicization in the federal public service, one partisan and the other structural. Partisan politicization and the integration of political staff within the public service through Sedion 39 ofThe Public Service Employment Act have become more common in recent years. The concept of structural politicization underlines how the Canadian public service is not politically neutral in the face of those wishing to undo the federal order. While it does not constitute an excuse that could justify the type of behaviour observed in the Groupaction affair, structural politicization provides a context for understanding why some public servants thought it could be legitimate to circumvent the rules in order to preserve national unity. L'auteur remercie son assistant de recherche, Michael Dumoulin, pour son efficacité et son esprit de détective.Il remercie également Leslie A. Pal, Herman Bakvis et André J. Béanger pour leurs commentaires sur la premiére version de ce texte présenté au congrés annuel de I'Association canadienne de science politique à Halifax en mai 2003. Il remercie enfin Madame Jocelyne Bourgon et les évaluateurs anonymes de la Revue. L'auteur se dit seul responsable de I'interprétation donnée aux événements entourant cette affaire, qui faisait toujours I'objet d'enquêtes policiéres au moment de la révision finale de cet article. … les hauts fonctionnaires chargéS de la gestion des contrats ont manifesté un mépris flagrant à I'égard de la Loi…ils ont contourné b peu prés toutes les règles. Sheila Fraser, Vérificatrice généraie du Canada     

International Patent Strategies of Small and Large Firms: An Empirical Study of Nanotechnology

The aim of this article is to investigate to what extent small‐firm foreign patents differ from those of their larger counterparts. The research setting consists of the population of U.S.‐owned small and large businesses with patent applications at the World International Patent Organization during 1996–2006 in the emerging field of nanotechnology. Findings reveal a significant and growing contribution of small firms to the globalization of patents. The analysis also suggests that small‐firm patents tend to be more novel and embedded in domestic innovation networks than large‐firm patents. Policy implications are multiple, including putting international patenting on the policy agenda and helping highly innovative small companies to explore foreign commercial opportunities in new markets of capital and technology.