Cyclic Pentanone Peroxide: Sensitiveness and Suitability as a Model for Triacetone Triperoxide

Research to counter the threat of organic peroxides such as triacetone triperoxide (TATP) is at times hampered by their inherent extreme sensitiveness and volatility. This work describes an approach to lowering some risks associated with the handling of TATP in the laboratory through the use of an analog species, tripentanone triperoxide (TPTP). Sensitiveness has been tested via standard methods. GCMS analysis has shown that TPTP degrades via similar mechanisms to TATP under a range of conditions. Slight differences in product composition were traced to side reactions which may also affect impurities present in homemade TATP synthesis. A pilot field trial was conducted to evaluate TPTP as a substitute for TATP in explosive detection dog (EDD) scent training. The degradation studies have yielded insights into the complexities of the acidic degradation of cyclic peroxides with potential forensic application, and TPTP's inadequacy as a TATP pseudoscent is a valuable example of the limitations of such training aids.     

Japan: the contested boundaries of alien suffrage at the local level

The provision of local level electoral rights in Japan for tokubetsu eijūsha (special permanent residents) and eijūsha (permanent residents) has sparked an ongoing controversy between opponents and proponents of extending the boundaries of suffrage. Periodically igniting for over a decade, the debate has involved politicians from across the political spectrum as well as local authorities, non-governmental organizations and academic scholars, yet remains locked into a cycle in which a period of optimism is followed by inaction and stagnation. In January 2008 the leader of the main opposition Democratic Party of Japan reignited the issue once more. Against this background, the goal of this paper is to highlight and trace the way in which the mainstream debate for and against electoral rights is being played out in the public arena. In so doing this paper makes two claims. First, we need to recognize the way that certain historical–social influences emanating from the processes of state-building since 1945 influence the current debates. Second, this must combine awareness of both legal/constitutional and normative aspects, as well as a sense of intra-party and inter-party political contestation.     

AFFECT,EMOTIONS AND SEX OFFENDING

The role of emotional and other affective states as causes and consequences of sexual offending is emerging as an important area for theoretical analysis and for empirical research. In this paper we focus on whether affective and emotional states serve as causal antecedents for sexual offending. Firstly, we identify five sources of evidence relating to whether emotion is causal. We conclude that the evidence broadly supports the notion that a causal relationship exists, at least for some offenders. We then address attempts to identify mechanisms to explain how such effects are mediated. Finally we discuss the implications of this work for therapeutic interventions with sex offenders.     

The process of change in offender rehabilitation programmes

Abstract

Whilst the overall effectiveness of offender rehabilitation programmes in reducing recidivism is now well established, there has been less discussion of the reasons why rehabilitation programmes may be unsuccessful for some offenders. In this paper we suggest that models of change developed in counselling and psychotherapy may have utility in explaining how offender rehabilitation programmes bring about change, and argue that the dominance of cognitive–behavioural treatments in the rehabilitation field means that those offenders who have particularly low levels of problem awareness may be at increased risk of treatment failure. Understanding more about the mechanisms by which programmes help offenders to desist from offending is likely to lead to the development of more responsive and, ultimately, more effective programmes. Some suggestions for those involved in the delivery of offender rehabilitation programmes include: being mindful of the sequence of components of programmes, the development of preparation (or readiness) programmes and offering a broad suite of programmes to cater for different stages of problem awareness and assimilation among offenders.     

Affective determinants of treatment engagement in violent offenders

Affective factors are likely to play a major role in determining the extent to which offenders are able to engage with, and benefit from, treatment. In this article, it is argued that the relationship between affect and treatment engagement may be understood in three ways: the access the client has to emotional states, the ability to express such states, and the willingness of the client to do this in the therapeutic session. It is suggested that affective determinants of treatment readiness can be understood with reference to models of emotional regulation and that attention to these affective factors in the early stages of treatment is likely to promote engagement, reduce attrition, and consequently improve treatment outcomes for violent offenders.     

Tertiary Education in Security and Policing in Australia

This paper reports on the current status of police and security education in Australian universities and technical colleges. The study was undertaken in the context of calls for greater professionalisation of policing and security along with a variety of conduct scandals that have driven reform agendas for both sectors. The study found that police studies had a significant profile in universities with a wide range of courses available, but virtually no profile in technical and further education (TAFE) colleges. Conversely, protective security offerings were proportionately more prominent in the TAFE sector than in universities. Courses in information and communication technology security were more common across universities and TAFE. The research also found that, of the 39 Australian universities, 9 have research centres related generally to policing and security. These also appeared to favour policing over security. We argue that these findings should be of concern, given the fact that private and public sector security services have eclipsed police, in numbers at least, in many jurisdictions. Security should, we argue, be counted as an equal partner with police in crime prevention services. In addition, we argue that those engaged in security management should be given greater opportunities for study at the university level. Moreover, security studies should have an expanded research focus.     

Adolescents’ Empathy and Prosocial Behavior in the Family Context: A Longitudinal Study

Children’s empathy and prosocial behavior play an important role in their social competence. Of the influential factors, research has demonstrated that parental behaviors and the quality of the parent–child relationship are important correlates of children’s development of empathy and prosocial behavior. The current study examined the associations between different types of parental behaviors (i.e., parental knowledge, parental solicitation, and parental psychological control), “balanced connectedness” in the parent–child relationship, which allows for both closeness and autonomy, and empathy and prosocial behavior in adolescents. The participants were 335 married couples (more than 80 % European American) and their adolescent child (49.0 % female; 10–13 years). Data were collected at three time points for parental behaviors, balanced parent–child connectedness, and adolescents’ empathy and prosocial behavior, respectively. The results of structural equation modeling suggested that adolescents’ perceptions of parental solicitation and parental psychological control may be associated with their empathy and prosocial behavior through their perceived balanced connectedness with parents. These findings suggest that enhancing balanced connectedness in the parent–child relationship may contribute to promoting empathy and prosocial behavior in adolescents over time. Further, this study suggests that parental solicitation may play a role in adolescents’ empathic and prosocial development, possibly depending on the quality of the parent–child relationship.     

THE ‘AUSSIE BATTLER’ AND THE HEGEMONY OF CENTRALISING WORKING-CLASS MASCULINITY IN AUSTRALIA

Abstract This paper explores the ways in which the ‘Aussie battler’ identity of the character Kenny Smyth in the film Kenny (2006) is both visible through its hegemonic status and cultural ubiquity, and invisible as the marker of normative Australian identity. This paper examines the ‘mainstream’ and ‘battler’ identities and the discourse that surrounds them, in particular looking at working-class masculinity which are argued to be both hegemonic and centralising. The paper explores how identities such as these, which exist at the axis of invisibility/visibility, can access narratives of entitlement and marginalisation. As a partially gendered and fully classed construct, the ‘battler’ identity operates within mainstream and mainstreaming culture in often exclusionary ways, denying any real challenge to classed and gendered inequality while using classed narratives to make a claim for more cultural, social and economic space.