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Solid-phase microextraction (SPME) is well documented with respect to its convenience and applicability to sampling volatiles. Nonetheless, fire debris analysts have yet to widely adopt SPME as a viable extraction technique, although several fire debris studies have demonstrated the utility of SPME coupled with gas chromatography-mass spectrometry (GC-MS) to identify ignitable liquids. This work considers the expansion of SPME sampling from the customary thermal desorption mode to solvent-based analyte desorption for the analysis of ignitable residues. SPME extraction fibers are desorbed in 30 microL of nonaqueous solvent to yield a solution amenable to conventional GC-MS analysis with standard autosampler apparatus. This approach retains the advantages of convenience and sampling time associated with thermal desorption while simultaneously improving the flexibility and throughput of the method. Based on sampling results for three ignitable liquids (gasoline, kerosene, anddiesel fuel) in direct comparisons with the widely used activated charcoal strip (ACS) method this methodology appears to be a viable alternative to the routinely used ACS method. 相似文献
134.
Donald M. Burke M. Ashley Ames Rosalie Etherington Jean Pietsch 《Journal of family violence》1990,5(3):199-207
A 2 × 4 × 4 factorial design was used to assess the effects of physical attractiveness in a domestic violence case. The attractiveness of both the defendant and victim were varied along four levels. Subjects were asked to read a domestic violence scenario where pictures of the defendant and victim were varied according their physical attractiveness. Results showed no significant effect of physical attractiveness in a juridic decision-making process in domestic violence. However, there were significant differences between male and female subjects in the sentencing of the defendant. This difference did not hold true for finding the defendant guilty or not guilty. 相似文献
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Investigating Residential History Using Stable Hydrogen and Oxygen Isotopes of Human Hair and Drinking Water 下载免费PDF全文
Madeleine Mant M.Sc. Ashley Nagel M.A. Tracy Prowse Ph.D. 《Journal of forensic sciences》2016,61(4):884-891
The relationship between isotopic signals in human hair and geographic region has potential forensic applications for identifying unknown individuals' place of recent residence. This study analyzes δ2H and δ18O isotopes in residential tap water and bulk hair samples from 17 volunteers representing 12 locations in Ontario, Canada. There is a strong correlation (R2 = 0.9) between δ2H and δ18O values of the water samples. In contrast, the δ2H and δ18O values of the hair samples are weakly correlated (R2 = 0.3), and the greater variability in the data is linked to dietary factors. This study demonstrates that the δ2H and δ18O values of hair and drinking water can be used to help identify potential place of residence in forensic cases, particularly in relation to proximity to large bodies of water such as the Great Lakes, but interpretations are complicated by the contribution of both water and diet to δ2H and δ18O values in hair. 相似文献
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Recent criminological scholarship on penal history museums has shown how sites of popular culture tend to silence the voices of prisoners and present them in ways that legitimate the deprivation of their liberty. While representations that reinforce the penal status quo are observable at most Canadian penal history sites, there are outliers that situate imprisonment as a form of oppression, and account for prisoners’ struggles and resistance. Drawing on three case studies from a 5-year qualitative research project on Canadian lock-up, jail, prison and penitentiary museums, we discuss what critical punishment memorialization looks like in a context of penal intensification in Canada. We show how such critical representations depend on the historical contextualization of penality as a manifestation of colonialism and/or the incorporation of prisoners’ voices and standpoint. We argue that the critical representations and narratives at these museum sites open up possibilities for the social distance between penal spectators and the incarcerated to be diminished by bringing humanizing prisoner narratives into focus in an otherwise dark tourist space. 相似文献
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Wellman Ashley Bisaccia Meitl Michele Kinkade Patrick Huffman Amanda 《American Journal of Criminal Justice》2021,46(2):317-344
American Journal of Criminal Justice - Larry Nassar, a once world renowned Olympic doctor, was arrested and charged with child abuse and child pornography in 2016, becoming one of the most prolific... 相似文献
139.
A Bayesian Approach to Age‐at‐Death Estimation from Osteoarthritis of the Shoulder in Modern North Americans 下载免费PDF全文
Ashley L. Brennaman M.S. Kim R. Love Ph.D. Jonathan D. Bethard Ph.D. James T. Pokines Ph.D. 《Journal of forensic sciences》2017,62(3):573-584
Osteoarthritis (OA) is a marker of degeneration within the skeleton, frequently associated with age. This study quantifies the correlation between OA and age‐at‐death and investigates the utility of shoulder OA as a forensic age indicator using a modern North American sample of 206 individuals. Lipping, surface porosity, osteophyte formation, eburnation, and percentage of joint surface affected were recorded on an ordinal scale and summed to create composite scores that were assigned a specific phase. Spearman's correlation indicated a positive relationship between each composite score and age (right shoulder = 0.752; left shoulder = 0.734). Transition analysis revealed a tendency toward earlier degeneration of the right shoulder. Bayesian statistics generated phase‐related age estimates based on highest posterior density regions. Best age estimates were into the seventh decade at the 90th and 50th percentile. The proposed method supplements traditional techniques by providing age estimates beyond a homogenous 50+ age cohort. 相似文献
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Ashley Williams Master of Social Work Master of Social Policy 《Juvenile & family court journal》2020,71(1):5-17
By examining previous literature on the brain’s developmental process during adolescence, this paper aims to determine how early childhood trauma potentially effects decision making in adolescence through exploring self-regulation theory. Through a self-regulation framework, the hope is to determine the connection, if any, between early childhood trauma, delinquent behavior, and involvement in the juvenile justice system. The author insists that not only do adolescents have less culpability due to their brain developmental stage compared to adults, but also early childhood trauma puts adolescents at a greater risk of impaired self-regulation which allows for more probable delinquent behavior. This paper also considers implications for social policy makers and youth advocates concerned with juvenile offenders tried in adult courts and existing racial disparities in the system. 相似文献