LC-MS/MS法检测圆珠笔墨迹中碱性蓝7及其去乙基产物的降解变化

目的考察圆珠笔墨迹中碱性蓝7及其去乙基产物的降解变化,为圆珠笔墨迹书写时间的研究提供基础数据。方法用氙灯老化碱性蓝7以生成其5个去乙基产物。建立LC-MS/MS检测碱性蓝7及其去乙基产物的方法。制作圆珠笔墨迹样本,在室内自然光照条件下老化3个月,同时进行控制实验条件的氙灯老化和高温老化实验。结果碱性蓝7的相对含量持续下降,其第一、第二级去乙基产物E4、E3的相对含量相继达到最大值,剩余三个去乙基产物E2、E1和E0的相对含量在三个月内持续增加。结论碱性蓝7的相对含量与光的辐照能量呈指数函数关系,其去乙基产物E4、E3的相对含量与光的辐照能量呈二次函数关系。不同油墨中碱性蓝7的老化曲线不同。温度对碱性蓝7的降解基本没有影响。     

自含墨印章印文盖印时间受老化条件的影响

目的探索利用气相色谱法较精确、定量测定自含墨印章印文盖印时间受人为老化条件的影响。方法分别在恒温烘烤、紫外线照射、纯水浸泡等人为老化条件下,测定自含墨印章印油中所含有的主要相关溶剂成份的含量变化。结果得出了主要溶剂成份在人为老化条件下其含量的变化规律以及人为老化与自然老化的对应关系。结论利用气相色谱法可以对不同保存条件下自含墨印章印文的盖印时间进行测定,为实际相关案件的检验提供了依据。     

利用红外显微镜无损检测圆珠笔油墨色痕的研究

在这个研究中,红外显微镜聚焦功能得到了充分验证。该研究采用的检测方法是通过红外显微镜将红外光斑直接聚焦在样品表面,采集其红外光谱。根据样品红外吸收峰的个数、位置、强度及形状进行定性分析,以达到区分相同颜色不同品牌的圆珠笔油墨色痕的研究目的。研究结果表明,采用的检测方法可有效区分相同颜色不同品牌的圆珠笔油墨色痕。而且该检测方法具有无损检测特点,保持了物证的原样性。     

Photoshop软件在印章印文比对检验中的应用

利用Photoshop软件的图像处理功能,对印章印文进行重叠比对,旨在为伪造印章印丈的简单比对以及检验鉴定提供一种思路。文中方法具有操作简便,精确性高的特点,可为检验鉴定工作做出初步判断。     

Effect of electron beam irradiation on forensic evidence. 2. Analysis of writing inks on porous surfaces

The effect of electron beam irradiation on a series of different writing inks is described. As the anthrax-tainted letters were discovered in October 2001, the U.S. government began to experiment with the use of the electron beam irradiation process for destroying such biological agents. Plans initially considered a large-scale countrywide use of this technology. However, over time the scope of this plan as well as the radiation dosage were reduced, especially when some adverse consequences to mailed items subjected to this process were observed. Little data existed at the time to characterize what level of damage might be expected to occur with common items sent through the mail. This was especially important to museums and other institutions that routinely ship valuable and historic items through the mail. Although the Smithsonian Institution initiated some studies of the effect of electron beam irradiation on archived materials, little data existed on the effect that this process would have on forensic evidence. Approximately 97 different black, blue, red, green, and yellow writing inks were selected. Writing ink types included ballpoint, gel, plastic/felt tip, and rollerball. All noncontrol samples were subjected to standard mail irradiation conditions used by the U.S. Postal Service at the time this experiment was performed. A video spectral comparator and thin-layer chromatography (TLC) analysis were used to evaluate both the control and the irradiated samples. Some published studies reported changes in the presence/absence of dye bands in the chromatograms of irradiated writing inks. Some of these studies report the formation of additional dye bands on the chromatogram while others report missing dye bands. However, using standard testing guidelines and procedures, none of the 97 irradiated inks tested were found to show any significant optical or chemical differences from the control samples. In addition, random testing of some of the ink samples using a second solvent system did not reveal any changes. However, one control ink did show some minor changes in optical properties and dye characteristics over time (but not TLC) while the irradiated sample remained stable. Significant changes in the ultraviolet fluorescence characteristics of the irradiated paper samples themselves (not inks) were also observed.     

显微共焦激光拉曼光谱仪分析激光打印黑色墨粉字迹

激光打印机是常用办公设备,案件中经常会涉及到激光打印文件的检验,运用显微共焦激光拉曼光谱仪检验激光打印黑色墨粉字迹是一种快速、无损、灵敏度高的检验方法,可以对墨粉成分进行定性分析,在司法实践中,此种方法对激光打印黑色墨粉具有较好的检验效果,应用前景广阔。     

一起通过利用Photoshop辨别印章真伪的检验

随着社会的迅猛发展,Photoshop等图像处理软件的运用普及程度越来越广泛。对基层公安机关而言,Photoshop功能的运用,不仅符合"科技强警"的要求,也为公安技术工作中解决文检的一些实际问题提供了新思路和新方法,特别是针对文检中印章印文检验,具有广泛的应用前景。     

Determination of the Sequence of Intersecting Lines Between Toners and Seals by Laser Fluorescence Microscope

Fluorescence microscope is considered to be one of the most effective ways to examine the sequence of intersecting seal and toner lines of questioned documents. In reality, however, the toner (mainly divided into compact and noncompact toners) and seal of a questioned document have such a complex morphology and sequence of crossing lines that current methods cannot meet the requirement of practical document identification. In view of the challenges of document examination, a laser fluorescence microscope and method are developed in this study. The developed microscope provides additional functionality to traditional fluorescence microscopes of transmitted light modality, laser excitation, selectable excitation wavelength, and selectable fluorescence filters. The results obtained from the method of comparisons between transmitted light and fluorescence modalities were positive under most conditions, particularly for noncompact toner examination for which a 100% accuracy rate and 90% detection rate were achieved in blind testing.     

Organizing a Proficiency Testing Program on Stamp Impressions Examination in Accordance with ISO/IEC 17043 Requirements

Stamps and stamp impressions examinations are based on matching defects and design details on the questioned and control samples. These examinations are routinely carried out by document examiners around the world. International proficiency tests for questioned documents examination have been available for decades while similar programs specifically focusing on stamp impressions examination are rare. This study reported a recent proficiency testing program on stamp impressions examination organized by an accredited provider in accordance with ISO/IEC 17043 requirements. Twenty‐four forensic laboratories registered for the program. Apart from giving details on the design and operation of the program, this study also aimed to provide the limitations and difficulties encountered in sample preparations, homogeneity, and stability tests of the testing materials. Various comments and feedbacks received from the participants, particularly in respect of examination approaches, challenges faced by the participants in forming conclusions and their suggestions for further improvement would be evaluated.     

Application of Raman Spectroscopy and Surface‐Enhanced Raman Scattering to the Analysis of Synthetic Dyes Found in Ballpoint Pen Inks*

Abstract: The applicability of Raman spectroscopy and surface‐enhanced Raman scattering (SERS) to the analysis of synthetic dyes commonly found in ballpoint inks was investigated in a comparative study. Spectra of 10 dyes were obtained using a dispersive system (633 nm, 785 nm lasers) and a Fourier transform system (1064 nm laser) under different analytical conditions (e.g., powdered pigments, solutions, thin layer chromatography [TLC] spots). While high fluorescence background and poor spectral quality often characterized the normal Raman spectra of the dyes studied, SERS was found to be generally helpful. Additionally, dye standards and a single ballpoint ink were developed on a TLC plate following a typical ink analysis procedure. SERS spectra were successfully collected directly from the TLC plate, thus demonstrating a possible forensic application for the technique.