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The Analysis of Colored Acrylic,Cotton, and Wool Textile Fibers Using Micro‐Raman Spectroscopy. Part 2: Comparison with the Traditional Methods of Fiber Examination
Authors:Patrick Buzzini Ph.D.  Genevieve Massonnet Ph.D.
Affiliation:1. Forensic and Investigative Science Department, West Virginia University, Morgantown, WV;2. Ecole des Sciences Criminelles, University of Lausanne, Dorigny, Lausanne, Switzerland
Abstract:In the second part of this survey, the ability of micro‐Raman spectroscopy to discriminate 180 fiber samples of blue, black, and red cottons, wools, and acrylics was compared to that gathered with the traditional methods for the examination of textile fibers in a forensic context (including light microscopy methods, UV‐vis microspectrophotometry and thin‐layer chromatography). This study shows that the Raman technique plays a complementary and useful role to obtain further discriminations after the application of light microscopy methods and UV‐vis microspectrophotometry and assure the nondestructive nature of the analytical sequence. These additional discriminations were observed despite the lower discriminating powers of Raman data considered individually, compared to those of light microscopy and UV‐vis MSP. This study also confirms that an instrument equipped with several laser lines is necessary for an efficient use as applied to the examination of textile fibers in a forensic setting.
Keywords:forensic science  criminalistics  trace evidence  Raman spectroscopy  Fourier transform infrared spectroscopy  Microscopy  Microspectrophotometry  thin‐layer chromatography  fibers  dye analysis
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