| 土制海洛因的薄层色谱扫描快速检验 |
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| 引用本文： | 贠克明,王玉瑾,李贵明,王英元,高艳霞,张勇. 土制海洛因的薄层色谱扫描快速检验[J]. 中国法医学杂志, 1999, 0(2) |
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| 作者姓名： | 贠克明 王玉瑾 李贵明 王英元 高艳霞 张勇 |
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| 作者单位： | 山西医科大学法医学系!太原030001(贠克明，王玉瑾，李贵明，王英元)，山西医科大学第二医院职业病科!太原030001(高艳霞)，山西省公安厅刑科所!太原030001(张勇) |
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| 基金项目： | 山西医科大学基金，山西省自然科学基金 |
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| 摘 要： | 建立土制海洛因的快速定性和定量检测方法。土制海洛因甲醇溶解，点于GF(254)薄层板上，正庚烷：氯仿：乙酸乙酯：乙醇：氨水（5：2：2：1．5：0．2）非饱和上行展开2次。薄层色谱扫描，Rf值结合斑点光谱扫描定性，色谱扫描定量。结果土制海洛因中主要成分海洛因、单乙酰吗啡、乙酰可待因、吗啡、可待因、蒂巴因、罂粟碱和那可汀分离完全，薄层扫描线性范围为0．2～2或4μg／斑点，最小检出量为0．1μg或0．2μg／斑点。本法可用于土制海洛因和海洛因的定性和定量检测。
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| 关 键 词： | 土制海洛因 薄层色谱扫描 |
A Rapid Identification of Self-mede Heroin by TLC Scan |
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| Yun Keming, Wang Yujin, LiGuiming and Wang Yingyuan. A Rapid Identification of Self-mede Heroin by TLC Scan[J]. Chinese Journal of Forensic Medicine, 1999, 0(2) |
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| Authors: | Yun Keming Wang Yujin LiGuiming Wang Yingyuan |
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| Abstract: | This paper in presented for the purpose of establish a rapid qualitative andquantitative analysis of self-made heroin.The self made heroin dissolued in methano wasadded to GF254 TLC plate, which was developed twice with n-heptane: trichloromethane:ethyl acetate: ethanol: ammonia solution (5: 2: 2: 1. 5: 0. 2 V: V). Thin layer chromato-graphy scan was carrvicd out for qualitative and quantitative analysis. Herion, monoacetyl-morphine, acetylocdeine, morphine, codeine, thebaine, papaverine and narcotine in self-made herion were separated completaly by TLC. The result showed that the standard curvesof principal alkaloids in self-made heroin were linear in the range of 0. 2 to 2 or 4 ug/spot bythe TLC scan. The minimal amount of detection were 0. 1ug or 0. 2/spot. This analyticmethod can be used in the identification of self-made herion as well as of herion and opium. |
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| Keywords: | Self-made herion TLC scan |
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