Primer residue analysis of ammunition of Indian origin by neutron activation analysis

The primer residues of ammunition manufactured in India have been analysed by neutron activation analysis (NAA). Since NAA is rather insensitive for lead, attention was confined to the elements antimony, barium, copper and mercury. The element/element combinations detected in significant amounts were (Sb), (Ba, Hg), (Ba, Cu, Sb), (Cu, Hg, Sb) and (Hg, Sb). The present study reveals the presence of Hg from mercury fulminate in priming compositions long discontinued in most ammunition of foreign origin. The presence of Hg can be advantageous in certain situations where the matrix on which the residue is deposited contains high levels of antimony such as clothing made of synthetic fibres. Caution is also required in interpreting the Cu values as being solely due to a jacketed projectile.