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A field diagnostic test for the improvised explosive urea nitrate
Authors:Almog Joseph  Klein Asne  Tamiri Tsippy  Shloosh Yael  Abramovich-Bar Sara
Affiliation:Casali Institute of Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel. Almog@vms.huji.ac.il
Abstract:A sensitive, specific and simple color test for the improvised explosive urea nitrate is described. It is based on the formation of a red pigment upon the reaction between urea nitrate and p-dimethylaminocinnamaldehyde (p-DMAC) under neutral conditions. Urea itself, which is the starting material for urea nitrate, does not react with p-DMAC under the same conditions. Other potential sources of false positive response e.g., common fertilizers, medications containing the urea moiety and various amines, do not produce the red pigment with p-DMAC. Exhibits collected from 10 terrorist cases have been tested with p-DMAC. The results were in full agreement with those obtained by instrumental techniques including GC/MS, XRD and IR.
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