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Comparison of Different Swabs for Sampling Inorganic Gunshot Residue from Gunshot Wounds: Applicability and Reliability for the Determination of Firing Distance
Authors:Daniele Merli Ph.D.  Alberto Amadasi M.D.  Debora Mazzarelli B.A.  Annalisa Cappella B.A.  Elisa Castoldi B.A.  Stefano Ripa B.A.  Lucia Cucca B.A.  Cristina Cattaneo Ph.D.  Antonella Profumo Ph.D.
Affiliation:1. Dipartimento di Chimica, Università degli Studi di Pavia, V.le Taramelli 12, 27100 Pavia, ItalyCorresponding author: Daniele Merli, Ph.D. E‐mail:;2. LABANOF, Laboratorio di Antropologia ed Odontologia Forense, Istituto di Medicina Legale e delle Assicurazioni, Università degli Studi di Milano, v. Mangiagalli 37, Milano, Italy;3. Dipartimento di Scienze Mediche e Chirurgiche, sede operativa di Medicina Legale, Università degli Studi di Bologna, Via Irnerio 49, 40126 Bologna, Italy;4. Dipartimento di Chimica, Università degli Studi di Pavia, V.le Taramelli 12, 27100 Pavia, Italy
Abstract:This study concentrates on samples of bare pork skin, with and without bristles, and dried bovine ribs shot with a semi‐automatic pistol to find the best methodology and sampling surface in the search for inorganic gunshot residues (IGSR). Four quadrants of known surface areas were sampled at different distances from the bullet's hole with different swabs: tapes in graphite, Leukosilk® white tape, 3M® transparent tape, and a cotton swab to assess the technique able to collect the highest amounts of IGSR with the lowest contribution of the blank. The cotton swab wet in 10% HNO3 gave the best results. The highest amounts of IGSR, measured by ICP‐OES and MS, were detected on a surface of 3‐cm radius from the bullet's edge. The amount of metals collected decreased with the firing distance between 20 and 60 cm. The procedure was efficient for sampling different tissues like skin and bones.
Keywords:forensic science  inorganic gunshot residues  inductively coupled plasma  firing distance estimation  sampling procedures  veterinary forensics
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