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Pyrolysis products of structure fires
Institution:1. Bureau of Alcohol, Tobacco and Firearms, San Francisco Laboratory Center, Treasure Island, CA 94130, USA;2. Institute of Forensic Sciences, Oakland, CA 94609, USA;1. Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Mianyang, China;2. Key Laboratory of Neutron Physics, Chinese Academy of Engineering Physics, Mianyang, China;1. Department of Fisheries, Faculty of Marine Natural Resources, Khorramshahr University of Marine Science and Technology, Khorramshahr, Khouzestan, Iran;2. Department of Physical Oceanography, Faculty of Marine Sciences, Khorramshahr University of Marine Science and Technology, Khorramshahr, Khouzestan, Iran;1. Dept. of Fire Protection Engineering, University of Maryland, College Park, MD, 20742, USA;2. Faculty of Engineering, China University of Geosciences, Wuhan, 430074, PR China
Abstract:Common floor-coverings, carpet, synthetic turf, vinyl flooring and pad (underlay) were exposed to a real-life fire environment consisting of an ordinary combustible fuel load in a room. Samples of the floor-coverings were recovered immediately after extinguishment and subjected to laboratory testing using heated head space and charcoal trap-carbon disulphide extraction. Polyethylene/polypropylene synthetic turf and polyurethane padding were found to present a significant volatile signature after such exposure. In a second test, several floor-coverings were burned in a room fire involving the use of three common petroleum products. None of the floor-coverings presented significant interference to identification of these accelerants in the post-fire debris; however, they were found to generate volatiles which might be mistaken for synthetic blends or specialist solvents. The difficulties and value of reproducing full-scale environments and their effects on combustibles are discussed.
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