签字笔笔痕同一认定充分条件的分析

签字笔因其具有书写流利、使用方便的特点，是现今最常见的书写工具之一。文章根据签字笔的结构特点和笔痕特征的形成机理，结合收集的96份实验样本，首次对签字笔笔痕进行同一认定应具备的充分条件进行初步研究，探讨了书写纸张施胶程度、衬垫物软硬程度、书写人运笔力度以及书写速度等书写条件因素的具体影响，同时研究了签字笔启用初期与末期书写笔痕特征可能出现的变化问题，总结出笔痕特征反映性、稳定性和特定性的具体特点，提出书写条件与书写笔的相近书写阶段均是签字笔笔痕同一认定充分条件的重要组成部分的观点，以期对文检工作者利用笔痕特征有一定的借鉴意义。     

滚珠型签字笔笔痕特征的实验研究

目的归纳总结滚珠型签字笔笔痕特征的分类,为笔迹鉴定人正确使用此类笔迹特征提供科学的参考依据。方法本研究采用科学实验的方法,对20人使用不同品牌的三支签字笔书写的笔迹进行了观察与分析。结果同一人使用不同的签字笔、不同人使用同一支签字笔和不同人使用不同的签字笔书写所形成的笔痕现象具有相同的表现。结论签字笔笔痕特征只是众多笔迹特征当中的一种,不能单独依据此类特征出具鉴定结论。     

个人的书写习惯对签字笔笔痕的影响

笔痕特征是文检笔迹鉴定的新方式,经过多年的应用实践,获得了较突出的成绩.笔迹鉴定新采用的笔痕特征检验,解决了特定书写笔与书写人同一认定的检验技术难题,提高了对少量字及笔画、摹仿等疑难字迹的检验效率.近年来,签字笔的普遍使用,让“书写习惯对签字笔笔痕的影响”这一课题变得必要.本文重点研究个人书写习惯对签字笔笔痕的特定性和稳定性的表现,有助于掌握利用笔痕特征进行同一认定的具体规律.     

签字笔与圆珠笔笔痕特征的比较研究

目的 探讨签字笔笔痕是否天然地适用圆珠笔笔痕检验条件而能够进行同一认定.方法 运用比较分析方法,在不同纸张条件下,以签字笔和圆珠笔为研究对象,收集288份有效实验样本,分别观察、记录、分析实验样本中的所产生的笔痕特征.结果 签字笔笔痕主要出现在大笔画的划痕特征；签字笔笔痕的稳定性和特定性要比圆珠笔弱.结论 签字笔笔痕同一认定需要考虑签字笔本身的特性,不可盲目鉴定.     

拉曼光谱成像技术检验朱墨时序中书写笔种类对检验结果的影响研究

目的考察在运用拉曼光谱阵列面扫描检验朱墨时序的方法中书写笔油墨种类对检验结果的影响。方法根据拉曼谱图的不同对搜集的188种书写笔（包括22种黑色圆珠笔,62种蓝色圆珠笔,62种黑色签字笔,42种蓝色签字笔）进行扫描并分类,采用拉曼光谱阵列面扫描技术对书写笔与同一印泥和印油形成的朱墨时序样本进行检验。结果 188种书写笔被分为4大类23小类,4类书写笔与印泥或印油形成的朱墨时序样本都得到了较好的检验结果。结论在本实验条件下,书写笔油墨种类对拉曼光谱阵列面扫描检验朱墨时序的检验结果没有影响。     

中性笔笔痕特征稳定性的实验分析

在阐明中性笔特点的基础上,通过对3位书写人用5支中性笔书写的90份实验材料的放大观察与测量,探讨中性笔笔痕特征在书写速度、书写姿势、书写衬垫物软硬、纸张洇散程度以及书写笔新旧程度不同时笔痕特征稳定性的具体表现,并分析影响笔痕特征稳定性的主要因素及变化规律。掌握影响中性笔笔痕特征稳定性具体因素及其变化规律,是有效利用中性笔笔痕特征进行笔迹鉴定的重要前提。     

高效液相色谱法鉴别蓝色签字笔墨水的种类

目的通过对签字笔字迹成分进行检验，达到对签字笔成分进行分离并对签字笔种类进行鉴定的目的。方法使用高效液相色谱法对蓝色签字笔字迹色痕中的色料成分进行分析，并依据分析结果对墨水的种类划分，同时考察了纸张的背景影响、最小用样量以及实验结果的重现性。结果22种蓝色签字笔样品均可以实现区分。结论本研究对实际应用有较大参考价值。     

拉曼光谱成像技术检验朱文时序时印文油墨种类对检验结果的影响

目的考察在运用拉曼光谱阵列面扫描检验朱文时序的方法中印文油墨种类对检验结果的影响。方法根据拉曼谱图的不同对搜集的21种印泥印油进行扫描并分类,采用拉曼光谱阵列面扫描技术对印泥印油与同一书写笔形成的朱文时序样本进行检验。结果 21种印泥印油被分为11类,21种印泥印油与蓝色签字笔形成的朱文时序样本都得到了良好的检验结果。结论印文油墨种类用拉曼光谱阵列面扫描检验朱文时序的检验结果没有影响。     

应用HPLC研究蓝色签字笔迹字迹色痕光老化规律

目的对蓝色签字笔所形成的字迹色痕光老化规律进行研究。方法比对14种蓝色签字笔样品在暗处保存条件下、自然光照射及强灯光照射等老化条件下物理特征变化情况;使用高效液相色谱法,监测蓝色签字笔墨水中色料成分的变化情况,并寻找蓝色签字笔墨水字迹自然光老化规律。结果强灯光照射后出现外观明显的老化现象,暗处存放的样本存在较长的老化时限。在自然光照射下30天内,样品色料成分的相对含量均随时间发生两个阶段的变化。结论样本字迹的外观为鉴定蓝色签字笔墨水字迹的形成时间提供了重要的信息。结合HPLC分析结果,可以确认字迹是否经过光照人工老化,为字迹形成时间鉴定的重要参考依据。     

基于银胶表面增强拉曼光谱检验蓝色书写字迹初探

目的用基于银胶的表面增强拉曼光谱技术检验蓝色签字笔字迹。方法取4种常见不同牌号的蓝色签字笔在其字迹上滴加微量银胶,用显微共焦拉曼光谱仪进行检验。结果不同品牌的蓝色签字笔字迹的表面增强拉曼光谱不同。结论基于银胶的表面增强拉曼光谱技术可用于纸张上蓝色签字笔字迹的检验。     

无交叉笔画状态下激光打印文字与中性笔书写文字形成时序的实验研究

目的探索无交叉笔画状态下激光打印文字与中性笔书写文字的时序特征及变化规律,以求运用于案件检验。方法以两种不同时序,请5名志愿者分别执不同中性笔在120张A4纸张上书写文字,并使用4台不同型号激光打印机打印文字,再运用奥博视频层晰显微镜对实验样本进行放大观察。结果证实在两种时序条件下制作的实验样本之间存在诸多差异性特征。结论这些差异性特征为准确判定无交叉笔画状态下激光打印文字与中性笔书写文字的时序提供了基础实验依据。     

Raman spectroscopy of blue gel pen inks

Raman spectroscopy is becoming a tool of major importance in forensic science. It is a non-invasive, non-destructive analytical method allowing samples to be examined without any preparation. This paper demonstrates the use of the technique as a general tool for gel pen inks analysis. For this purpose, 55 blue gel pen inks, of different brands and models representative of gel pen available on the world market at the time of this study, were collected. A preliminary solubility test in methanol allowed separating them into two classes: 19 dye-based and 36 pigment-based gel inks. The latter were analysed by Raman spectroscopy (RS) using two wavelength laser sources (514.5 and 830 nm). Two main pigments were identified, pigment blue 15 and pigment violet 23.     

A study to investigate the evidential value of blue gel pen inks

The aim of this project was to investigate the evidential value of blue gel pen inks in Europe. For this purpose, 33 blue gel pen inks, of different brands and models, representative of those available on the European market at the time of the study, were analyzed using three techniques: filtered light examination (FLE), Raman Spectroscopy (RS), and scanning electron microscopy (SEM). First, after visual examination (naked eye and stereo microscope), it was possible to classify the 33 inks into three groups described as: milky, metallic, and normal. This paper describes in detail the results obtained for the normal gel pen group. The ability of the techniques to discriminate gel inks between and within brands varied. The results indicated that RS and SEM were more discriminating than FLE. The greatest degree of differentiation was achieved when using a combination of RS and SEM techniques (discriminating power = 0.91). This study also highlights some problems concerning the identification of the brand of a gel pen from a written text.     

Forensic discrimination of blue ballpoint pen inks based on thin layer chromatography and image analysis

This article aims to provide a new and fast method for differentiation of inks on a questioned document. The data acquisition was carried out by designing specific image analysis software for evaluating thin layer chromatograms (TLC-IA). The ink spot was extracted from the document using methanol and separated by TLC using plastic sheet silica gel 60 without fluorescent indicator, and a mixture of ethyl acetate, ethanol, and water (70:35:30, v/v/v) as mobile phase. To discriminate between different pen inks, new software was designed on the basis of intensity profile of red, green, and blue (RGB) characteristic. In practice, after development of chromatogram, the chromatograms were scanned by ordinary office scanner, intensity profiles of RGB characteristics on the development straight of each sample were produced and compared with the mentioned software. RGB profiles of ballpoint inks from various manufacturers showed that the patterns in most cases were distinctly different from each other. This new method allowed discriminating among different pen inks with a high reliability and the discriminating power of 92.8%. Blue ballpoint pen inks of 41 different samples available on the local market were successfully analyzed and discriminated.     

Determining the sequence of intersecting gel pen and laser printed strokes — A comparative study

The relative chronological sequence of intersecting gel pen ink lines and laser printed marks has been determined using optical methods. The results were obtained by observing spectral reflection, relative sheen, skipping and gaps of gel pen ink strokes at the point of intersection. The intersections are observed under stereomicroscope and digital microscope. The effectiveness of both the optical instruments for sequence of the strokes has been compared. The sequence of intersecting lines (of same colour, different colours and where one of the strokes is darker) has been established.     

薄层色谱法鉴别黑色中性笔色痕的种类

黑色中性笔墨水主要由溶剂、色料、增稠剂、稳定剂和其他添加剂等组成,不同厂家或同厂家不同牌号中性笔墨水的成分不同,尤其是色料差别较大,这为中性笔墨水的种类鉴别提供了依据。本文利用数理统计中的均匀设计法和正交设计法安排试验,建立了一种可用于黑色中性笔色痕种类鉴别的方法:用N,N-二甲基甲酰胺作为黑色中性笔色痕的提取剂,四氢呋喃:甲醇:1,2-二氯乙烷:氯仿=30:15:5:7为展开剂的薄层色谱分析法。     

Determination of the Chronological Order of a Laser Printing and Gel Pen Writing Without any Crossing Strokes

Laser printers and writing instruments are being exploited by the forgers to produce fabricated documents. They often produce such documents by appending genuine signature on a blank sheet and later printing on it. Often these fabricated documents do not contain intersection of strokes and may pose a difficulty to forensic document examiners in analyzing cases related to such documents. Keeping in mind the limited research work done on nonintersecting strokes, the present study has been conducted with an aim to determine the sequence of nonintersecting strokes of gel pens and laser printers. Three hundred samples of nonintersecting strokes of gel pen ink and laser printing were prepared. Of these 300, 150 had laser-printed text below the gel pen strokes and the remaining 150 were prepared with gel pen stokes below the laser-printed text. The samples have been analyzed using Nikon SMZ 800N stereomicroscope. Three micro-conformation features, that is, pattern of toner distribution, ink distribution, and fiber distribution have been observed in the samples. The results demonstrate the successful establishment of sequence of nonintersecting strokes in case of gel pen and laser-printed documents by the determination of micro-conformation features.     

A statistical methodology for the comparison of blue gel pen inks analyzed by laser desorption/ionization mass spectrometry

A statistical methodology for the objective comparison of LDI-MS mass spectra of blue gel pen inks was evaluated. Thirty-three blue gel pen inks previously studied by RAMAN were analyzed directly on the paper using both positive and negative mode. The obtained mass spectra were first compared using relative areas of selected peaks using the Pearson correlation coefficient and the Euclidean distance. Intra-variability among results from one ink and inter-variability between results from different inks were compared in order to choose a differentiation threshold minimizing the rate of false negative (i.e. avoiding false differentiation of the inks). This yielded a discriminating power of up to 77% for analysis made in the negative mode. The whole mass spectra were then compared using the same methodology, allowing for a better DP in the negative mode of 92% using the Pearson correlation on standardized data. The positive mode results generally yielded a lower differential power (DP) than the negative mode due to a higher intra-variability compared to the inter-variability in the mass spectra of the ink samples.