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签字笔水、圆珠笔油红外发光特性的研究 总被引:2,自引:0,他引:2
目的记录不同激发光、接收滤光镜下,各种油墨红外发光强弱的程度,为文字检验提供基础性的研究。方法用多波段光源中510~650nm单色光激发各种油墨样本,全波段物证检验CCD系统记录样本在530~950nm接收滤光镜下出现的红外发光图像。结果多数油墨在接收滤光镜到达800~850nm时,呈现出强烈的红外发光状态,并随接收波段的上升而开始衰减。结论可利用某些油墨的发光与否,发光强与弱的特性,检验案件中涂改和涂抹字迹。 相似文献
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1全波段CCD物证检验系统简介
特种照相作为现阶段用来提取现场潜在痕迹物证的重要手段,主要包括红外照相、紫外照相、发光照相和偏振光照相等,不同的方法需要用不同的器材来实现,这些器材包括多波段光源、紫外成像仪、红外成像仪、紫外光源、红外光源、偏振光摄影灯、各种波长的滤光镜等,器材繁多,操作繁琐。 相似文献
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目的建立利用傅里叶红外图像系统无损检验添改数字的检验方法。方法采集同种同品牌、同种不同品牌及不同种书写材料书写的数字1改为4和3添加为8两类样本的红外图像,根据红外吸收的光谱信息对其添改进行检验。结果同种不同品牌及不同种书写材料对红外吸收强弱不同,形成的红外图像有差别;同种同品牌书写材料对红外吸收强弱没有明显差别。结论该检验方法不损坏检材,重现性好,并且纸张成分对其分析结果基本上无干扰。 相似文献
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作为专门为法学犯罪现场勘查而设计的ST55型手提式氙灯多波段光源,可提供14个不同的输出波段光以供选择,为公安机关侦破案件、打击犯罪提供了有力帮助。其显现痕迹物证的基本原理主要包括两个方面:一是依据形成痕迹中的某些物质(如汗液手印中的汗液)在某波段输出光源的照射下, 相似文献
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目的对蓝色签字笔所形成的字迹色痕光老化规律进行研究。方法比对14种蓝色签字笔样品在暗处保存条件下、自然光照射及强灯光照射等老化条件下物理特征变化情况;使用高效液相色谱法,监测蓝色签字笔墨水中色料成分的变化情况,并寻找蓝色签字笔墨水字迹自然光老化规律。结果强灯光照射后出现外观明显的老化现象,暗处存放的样本存在较长的老化时限。在自然光照射下30天内,样品色料成分的相对含量均随时间发生两个阶段的变化。结论样本字迹的外观为鉴定蓝色签字笔墨水字迹的形成时间提供了重要的信息。结合HPLC分析结果,可以确认字迹是否经过光照人工老化,为字迹形成时间鉴定的重要参考依据。 相似文献
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Andrasko J 《Journal of forensic sciences》2001,46(1):21-30
A method for comparison of ink entries on documents stored in different light conditions is presented. Various blue inks were exposed to light, both daylight and artificial light from fluorescent tubes. Inks were then extracted from the document and analyzed by HPLC (high performance liquid chromatography). Significant changes in composition were noted on exposure to light. These changes were followed by using ternary diagrams constructed for dyes generally present in blue-colored inks--Crystal Violet, Methyl Violet, and Tetramethyl Para Rosaniline. Also, the amount of the various compounds formed by decomposition of these dyes on exposure to light was measured and employed for comparison of inks. An example of the use of the proposed method in casework is given. 相似文献
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Mohamed Mabrouk El‐Molla Ph.D. Sayed Ahamed Shama Ph.D. Saeed El‐Sayed Saeed M.Sc. 《Journal of forensic sciences》2013,58(1):188-194
Abstract: Disappearing inks have been used in different fields, but it may be abused in forgery and counterfeiting. This research was conducted on the preparation of disappearing inks using different concentrations of thymolphthalein, phenolphthalein, and their mixture. The prepared inks were applied to different types of handwriting papers. It was found that the handwriting stability increased by increasing thymolphthalein, phenolphthalein, or alkali concentration, but in the case of using 4 mL of 1 normal (N) NaOH, the handwriting stability of phenolphthalein and its mixture inks decreased. Deciphering of the faded handwriting was evaluated by different methods; using optical deciphering, the faded handwriting did not respond to the different light sources. All the faded handwriting was visible when treated with alkaline solution. There was no change in the faded handwriting when heated to 100°C; phenolphthalein and mixture inks containing 0.5 mL of 1 N NaOH became red when only Azhar and Xerox papers were heated to 150°C. 相似文献
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A method based on profiling of dye components by electrospray ionization mass spectrometry (ESI/MS) is described for the characterization of ballpoint pen inks. The method involves benzyl alcohol (30 microL) extraction of ink from paper. The extracts of ink lines 1 and 5 mm in length are used for direct ESI/MS analysis in positive and negative modes, respectively. The instrumental analysis takes 3 min. Basic and acid dyes in the inks are detected in the positive and negative modes, respectively, with each dye yielding one or two characteristic ion peaks. The mass spectrum, which is mainly a compositional signature of the dyes in the ink, was not affected by the type of paper from which the ink was extracted, or by natural ageing of the ink on document in the absence of light. However, exposure to fluorescent illumination caused dealkylation of polyalkylated basic dyes and resulted in changes in the homologous distribution of the dyes. In this study, a total of 44 blue inks, 23 black inks, and 10 red inks have been analyzed, and the mass spectra were used to establish a searchable library. ESI/MS analysis provides a simple and fast way to compare ink specimens and in combination with on-line library search permits rapid screening of inks for forensic document investigations. 相似文献
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Identification of colorants in pigmented pen inks by laser desorption mass spectrometry 总被引:1,自引:0,他引:1
Pigments are rapidly replacing dyes as colorants in pen and printer inks, due to their superior colors and stability. Unfortunately, tools commonly used in questioned document examination for analyzing pen inks, such as TLC, cannot be used for the analysis of insoluble pigments on paper. Laser desorption mass spectrometry is demonstrated here as a tool for analyzing pigment-based pen inks. A pulsed nitrogen laser can be focused onto a pen stroke from a pigmented ink pen on paper, and positive and negative ions representative of the pigment can be generated for subsequent mass spectrometric analysis. Targeted pens for this work were a set of Uni-ball 207 pigmented ink pens containing blue, light blue, orange, green, violet, red, pink, and black inks. Copper phthalocyanine was identified as the pigment used to make both blue inks. A mixture of halogenated copper phthalocyanines were identified in the green ink. Unexpectedly, the pink ink was found to contain a red pigment, Pigment Red 12, treated with a mixture of water-soluble dyes. Each sample yielded ions representative of the pigments present. 相似文献
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Detection of chemical erasure and differentiation of inks by examination under long- and short-wave ultraviolet light generally solves many Questioned Documents problems. Many dyestuff-based inks fluoresce when examined under ultraviolet light, when the dye component fluoresces under the direct ultraviolet light. Sometimes, however, this fluorescence becomes quenched when the dye becomes bonded to some other, non-fluorescent compound, and does not fluoresce under ultraviolet rays. When the dye is freed from its bonded state it regains its fluorescence.In a recent case, two specimens of writing in ink of apparently the same colour were differentiated when aqueous spots of the ink from the disputed and original entries were transferred direct to a filter paper and examined under ultraviolet rays. The spots from the fraudulent entry fluoresced under the ultraviolet, but not the spots from the original entry. Neither the original nor the fraudulent entry showed any fluorescence when examined directly under ultraviolet light. 相似文献
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Thin layer chromatography (TLC) is a scientific methodology that can be used to compare and characterize ink formulations. Occasionally, when evaluating chromatographic profiles on a TLC plate with ambient light, different ink formulations, or the same inks from different batches, may appear indistinguishable. The use of filtered light can be very effective to illuminate characteristics that are not readily apparent with ambient light. There are a diverse number of components commonly found in writing inks, and it may be that some of them respond to particular wavelengths of energy that are not visible to the unaided eye (i.e., colorless). There has been very little information published that addresses the use of filtered light for evaluating TLC plates. Twenty-nine ballpoint writing ink samples were selected for TLC analysis. Further evaluation using an alternate light source, coupled with the appropriate filter, proved to be an effective means for definitive discrimination in some cases. 相似文献
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《Forensic science international》1999,101(3):167-176
The aim of this project was to investigate the evidential value of blue and black ballpoint pen inks in Australia. For this purpose, 49 blue and 42 black ballpoint pen inks, of different brands, models and batches, representative of those ballpoint pens available on the Australian market at the time of the study, were analysed by three techniques: filtered light examination (FLE); reflectance visible microspectrophotometry (MSP); and thin-layer chromatography (TLC). The results showed that the power of the individual techniques to discriminate inks between and within brands, models and batches varied, the most informative techniques being TLC>FLE>MSP. The greatest degree of differentiation was achieved when using a combined sequence of techniques, the discriminating power being 0.99 and close to 1 for blue and black inks, respectively (different brands and models). In respect to the discrimination between different batches of a same brand and model, it was shown that 14 out of the 33 pairs compared could be discriminated. Overall, this study confirmed the high value of the examination of inks when applied to ballpoint pens available in Australia, especially when a combined sequence of techniques is applied. 相似文献